ClO4 -- directed Assembly of Two CoII Complexes Based on Flexible N-donor Ligands: Syntheses, Crystal Structures and Magnetic Properties

被引：0
作者：
Wen Guo-Xuan [1 ,2 ]
Dong Wen-Wen [1 ]
Pan Li-Qing [2 ]
Li Dong-Sheng [1 ]
机构：
[1] China Three Gorges Univ, Coll Mat & Chem Engn, Hubei Prov Collaborat Innovat Ctr New Energy Micr, Yichang 443002, Peoples R China
[2] China Three Gorges Univ, Coll Sci, Yichang 443002, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Co-II complex; interpenetrating network; crystal structure; magnetic properties; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; HYDROTHERMAL SYNTHESIS; MOF; NETWORKS; TOPOLOGY; NETS;
D O I：
10.14102/j.cnki.0254-5861.2011-1266
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of Co-II ions with 1,4-bis(imidazol)butane (bimb) or 1,4-bis(triazol)bu-tane (bitb) in the presence of ClO4-, respectively affords two CoII coordination complexes, namely {[Co (bimb)(3)]center dot 2ClO(4)}(n) (I) and {[Co (bitb)(3)]center dot 2ClO(4)}(n) (II). Single-crystal X-ray analysis indicates that both complexes I and II show the same alpha-Po topological structures. However, complex I exhibits a 2-fold interpenetrating network, while complex II features a 3-fold interpenetrating network. In addition, solid-state properties such as thermal stabilities and magnetic properties of two complexes were also investigated.
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页码：89 / 98
页数：10
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