Biochar from carrot residues chemically modified with magnesium for removing phosphorus from aqueous solution

被引:78
作者
Eufrasio Pinto, Marina de Carvalho [1 ]
da Silva, Demetrius David [1 ]
Amorim Gomes, Ana Luiza [2 ]
Menezes dos Santos, Rodrigo Morais [2 ]
Alves de Couto, Ricardo Alexandre [3 ]
de Novais, Roberto Ferreira [2 ]
Leopoldo Constantino, Vera Regina [3 ]
Tronto, Jairo [2 ]
Pinto, Frederico Garcia [2 ]
机构
[1] Univ Fed Vicosa, Dept Agr Engn, Campus Univ, BR-36570000 Vicosa, MG, Brazil
[2] Univ Fed Vicosa, Inst Exact Sci, Campus Rio Paranaiba,Rodovia BR 354,Km 310, BR-38810000 Rio Paranaiba, MG, Brazil
[3] Univ Sao Paulo, Inst Chem, Dept Fundamental Chem, Av Lineu Prestes 748, BR-05508000 Sao Paulo, SP, Brazil
关键词
Biochar; Carrot; Agriculture residue; Phosphorus; AL-MODIFIED BIOCHAR; PHOSPHATE ADSORPTION; ENGINEERED BIOCHAR; RECLAIMING PHOSPHATE; WASTE-WATER; PYROLYSIS; AMMONIUM; NITRATE; SOIL; NANOCOMPOSITES;
D O I
10.1016/j.jclepro.2019.03.012
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The continuous increase in the world population requires more agricultural production; therefore, phosphorus compounds (P) are essentials. Considering that P reserves are finite, studying its recycling and reusing is essential. Biochar made from agricultural residues is an interesting material to be studied for P recovery and reuse in agriculture. This study shows the preparation and characterization of a biochar obtained from the pyrolysis of carrot residue for P adsorption studies in aqueous solution. Carrot was pyrolyzed at different temperatures values, with and without pretreatment with MgCl2. Biochar impregnated with Mg and pyrolyzed at 400 degrees C showed higher efficiency in P removal in aqueous solution (138 mg g(-1)). The characterization techniques indicated that after P adsorption by biochar, a chemical reaction occurred between Mg and P species with formation of Mg(H2PO4)(2). The biochar from carrot residue obtained in this work is a promising adsorbent for P recycling and has potential to be used as soil fertilizer. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码:36 / 46
页数:11
相关论文
共 47 条
[1]  
Aguiar C., 2015, REV BRASILEIRA RECUR, V20, P1093, DOI [https://doi.org/10.21168/rbrh.v20n4.p1093-1102, DOI 10.21168/RBRH.V20N4.P1093-1102]
[2]   Biochar as a sorbent for contaminant management in soil and water: A review [J].
Ahmad, Mahtab ;
Rajapaksha, Anushka Upamali ;
Lim, Jung Eun ;
Zhang, Ming ;
Bolan, Nanthi ;
Mohan, Dinesh ;
Vithanage, Meththika ;
Lee, Sang Soo ;
Ok, Yong Sik .
CHEMOSPHERE, 2014, 99 :19-33
[3]  
Amonette J. E., 2009, BIOCHAR ENV MANAGEME, P34
[4]  
[Anonymous], 2007, CERNE
[5]  
[Anonymous], 2007, D176284 ASTM INT
[6]   Effect of biochar amendment on greenhouse gas emission and bio-availability of heavy metals during sewage sludge co-composting [J].
Awasthi, Mukesh Kumar ;
Wang, Quan ;
Huang, Hui ;
Li, Ronghua ;
Shen, Feng ;
Lahori, Altaf Hussain ;
Wang, Ping ;
Guo, Di ;
Guo, Zhanyu ;
Jiang, Shuncheng ;
Zhang, Zengqiang .
JOURNAL OF CLEANER PRODUCTION, 2016, 135 :829-835
[7]  
Braga J.M., 1974, Revista Ceres, V21, P73, DOI DOI 10.1021/I560101A038
[8]   A novel magnetic biochar efficiently sorbs organic pollutants and phosphate [J].
Chen, Baoliang ;
Chen, Zaiming ;
Lv, Shaofang .
BIORESOURCE TECHNOLOGY, 2011, 102 (02) :716-723
[9]   Cow dung-derived engineered biochar for reclaiming phosphate from aqueous solution and its validation as slow-release fertilizer in soil crop system [J].
Chen, Qincheng ;
Qin, Jiaolong ;
Sun, Peng ;
Cheng, Zhiwen ;
Shen, Guoqing .
JOURNAL OF CLEANER PRODUCTION, 2018, 172 :2009-2018
[10]   Carbon Stability of Engineered Biochar-Based Phosphate Fertilizers [J].
da Silva Carneiro, Jefferson Santana ;
Lustosa Filho, Jose Ferreira ;
Nardis, Barbara Olinda ;
Ribeiro-Soares, Jenaina ;
Zinn, Yuri Lopes ;
Azevedo Melo, Leonidas Carrijo .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (11) :14203-14212