Photocatalytic degradation of textile dye X-3B using TiW11Ti/SiO2 hybrid materials

被引:12
作者
Ai, Limei [1 ]
Zhang, Danfeng [1 ]
Wang, Qiang [1 ]
Yan, Jingsen [1 ]
Wu, Qingyin [1 ,2 ]
机构
[1] Liaoning Inst Sci & Technol, Sch Biomed & Chem Engn, Benxi 117004, Liaoning, Peoples R China
[2] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
关键词
Composite materials; Heteropoly acid; Polyoxometalate; Sol-gel method; Photocatalytic degradation; HETEROPOLY ACID; POLYOXOMETALATE; PERFORMANCE; COMPOSITE; CONDUCTIVITY; CATALYST; SILICA; SALT; GEL;
D O I
10.1016/j.catcom.2019.04.007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Various photocatalysts composed of undecatungstotitanotitanic heteropoly acid (H-4[Ti(H2O)TiW11O39]center dot 7H(2)O) loaded on silica (TiW11Ti/SiO2) were prepared by sol-gel method. The TiW11Ti/SiO2 hybrid materials were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and Diffuse reflectance spectra (DRS). The photocatalytic performance was investigated by photocatalytic degradation of brilliant dye X-3B under ultraviolet light irradiation. The TiW11Ti/SiO2 hybrid showed higher photocatalytic activity than pure TiW11Ti and TiW11Ti + SiO2 (TiW11Ti mixed simply with SiO2). Among three different loading weights of TiW11Ti for the hybrids, the degradation efficiencies of dye X-3B displayed the following order: 45 wt% > 30 wt% > 60 wt%.
引用
收藏
页码:10 / 14
页数:5
相关论文
共 30 条
[1]   Synthesis and conductive performance of polyoxometalate acid salt gel electrolytes [J].
Ai, Limei ;
Wang, Zeqing ;
He, Fengwei ;
Wu, Qingyin .
RSC ADVANCES, 2018, 8 (59) :34116-34120
[2]   Influence of polyoxometalate structure in ammoxidation of 2-methylpyrazine [J].
Al-Shehri, Abdulmohsen ;
Katabathini, Narasimharao .
CATALYSIS COMMUNICATIONS, 2018, 108 :17-22
[3]   Covalent hybrids based on Re(I) tricarbonyl complexes and polypyridine-functionalized polyoxometalate: synthesis, characterization and electronic properties [J].
Auvray, Thomas ;
Santoni, Marie-Pierre ;
Hasenknopf, Bernold ;
Hanan, Garry S. .
DALTON TRANSACTIONS, 2017, 46 (30) :10029-10036
[4]   Composite H3PW12O40-TiO2 catalysts for toluene selective photo-oxidation [J].
Bertolini, Guillermo R. ;
Pizzio, Luis R. ;
Kubacka, Anna ;
Munoz-Batista, Mario J. ;
Fernandez-Garcia, Marcos .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 225 :100-109
[5]   Design and fabrication of memory devices based on nanoscale polyoxometalate clusters [J].
Busche, Christoph ;
Vila-Nadal, Laia ;
Yan, Jun ;
Miras, Haralampos N. ;
Long, De-Liang ;
Georgiev, Vihar P. ;
Asenov, Asen ;
Pedersen, Rasmus H. ;
Gadegaard, Nikolaj ;
Mirza, Muhammad M. ;
Paul, Douglas J. ;
Poblet, Josep M. ;
Cronin, Leroy .
NATURE, 2014, 515 (7528) :545-549
[6]   Skeletal isomerization of n-heptane with highly selective Pt/H3PW12O40/SBA-15 trifunctional catalysts [J].
de la Fuente, N. ;
Wang, J. A. ;
Chen, L. F. ;
Gonzalez, J. ;
Salmones, J. ;
Contreras, J. L. ;
Navarrete, J. .
CATALYSIS COMMUNICATIONS, 2017, 102 :93-97
[7]   Polyoxometalate based mesoporous acidic catalyst from biogenic silica for vegetable oil methanolysis: Structure activity relationship study [J].
Dutta, Raju ;
Singh, Sunit Kumar ;
Mandavgane, Sachin A. ;
Ekhe, Jayant D. .
APPLIED CATALYSIS A-GENERAL, 2017, 539 :38-47
[8]   First organic-inorganic hybrid nanomaterial constructed from a Keggin-type polyoxometallate and a copper-dithiocarbamate complex: Sonochemical synthesis, crystal structure and its adsorption performance for organic dye pollutants [J].
Farhadi, Saeed ;
Dusek, Michal ;
Siadatnasab, Firouzeh ;
Eigner, Vaclav ;
Andani, Abbasali Mokhtari .
POLYHEDRON, 2017, 126 :227-238
[9]   Improved (Photo) catalytic Propene Hydration in a Gas/Solid System by Using Heteropolyacid/Oxide Composites: Electron Paramagnetic Resonance, Acidity, and Role of Water [J].
Garcia-Lopez, Elisa I. ;
Marci, Giuseppe ;
Pomilla, Francesca R. ;
Liotta, Leonarda F. ;
Megna, Bartolomeo ;
Paganini, Maria C. ;
Gionco, Chiara ;
Giamello, Elio ;
Palmisano, Leonardo .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (13) :1900-1907
[10]   Ligand-Controlled Assembly of Heteropolyoxomolybdates from Plenary Keggin Germanomolybdates and Cu-Ln Heterometallic Units [J].
Gong, Pei-Jun ;
Pang, Jing-Jing ;
Hu, Hui-Fen ;
Li, Hui-Jie ;
Chen, Li-Juan ;
Zhao, Jun-Wei .
CHEMISTRY-AN ASIAN JOURNAL, 2018, 13 (23) :3762-3775