Synthesis of lutetium(III)-porphyrin complexes: old problems and new excellent conditions found

被引：2

作者：

Kalota, Bartosz ^{[1
]}

Mikus, Agnieszka ^{[2
]}

Ostrowski, Stanislaw ^{[2
]}

机构：

[1] Jan Dlugosz Univ Czgstochowa, Inst Chem Environm Protect & Biotechnol, Al Armii Krajowej 13-15, PL-42200 Czestochowa, Poland

[2] Uniwersytet Przyrodniczo Humanistyczny Siedlcach, Inst Chem, Ul 3 Maja 54, PL-08110 Siedlce, Poland

来源：

NEW JOURNAL OF CHEMISTRY | 2016年 / 40卷 / 12期

关键词：

LANTHANIDE(III) MONOPORPHYRINATE COMPLEXES; RESONANCE DIPOLAR PROBE; PORPHYRIN COMPLEXES; NUCLEOPHILIC-SUBSTITUTION; ELECTROPHILIC NITRATION; PYRROLE UNIT; SIMPLE ROUTE; LUMINESCENCE; HYDROGEN; TETRAARYLPORPHYRINS;

D O I：

10.1039/c6nj02424f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A convenient method for the preparation of very attractive and almost unknown lutetium(III)-porphyrins was developed. Systematic investigations involving a broad spectrum of solvents (DMF, TCB, imidazole, sulfolane, and a CHCl3/MeOH mixture), as well as studies concerning the influence of temperature and the reaction time on the yield, were performed. Under the optimized experimental conditions found within the study for [5,10,15,20-tetraphenylporphyrinato]lutetium(III) chloride (sulfolane, reflux, 0.5 h; 88% yield), the synthesis of some other more complex derivatives was demonstrated.

引用

页码：9899 / 9902

页数：4

共 50 条

[41] SYNTHESIS AND MAGNETIC-RESONANCE SPECTROSCOPY OF NOVEL PHENOLATO-BRIDGED MANGANESE(III) AND IRON(III) MANGANESE(III) PORPHYRIN COMPLEXES
GODZIELA, GM
TILOTTA, D
GOFF, HM
INORGANIC CHEMISTRY, 1986, 25 (13) : 2142 - 2146
[42] 1,2-Azaborolyl-Ligated Half-Sandwich Complexes of Scandium(III) and Lutetium(III): Synthesis, Structures, and Syndiotactic Polymerization of Styrene
Fang, Xiangdong
Li, Xiaofang
Hou, Zhaomin
Assoud, Jalil
Zhao, Rui
ORGANOMETALLICS, 2009, 28 (02) : 517 - 522
[43] Synthesis of new pyridinofullerene ligands capable of forming complexes with zinc tetraphenyl porphyrin
Xiang, Yun
Wei, Xian-Wen
Zhang, Xin-Ming
Wang, Hai-Ling
Wei, Xiang-Long
Hu, Ji-Ping
Yin, Gui
Xu, Zheng
INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (05) : 452 - 455
[44] Synthesis and Characterization of a New Unsymmetrical Porphyrin Liquid Crystal and Its Metal Complexes
Zhuang, C. -F.
Tang, X. -X.
Wang, D.
Lian, W. -H.
Xia, A. -Q.
Shi, Y. -H.
Shi, T. -S.
POLISH JOURNAL OF CHEMISTRY, 2009, 83 (12) : 2205 - 2213
[45] Synthesis and triiron complexes of PDK, a new porphyrin-linked dicarboxylate ligand
Zhang, XX
Fuhrmann, P
Lippard, SJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (39) : 10260 - 10261
[46] Synthesis and characterization of a new unsymmetrical porphyrin liquid crystal and its lanthanide complexes
Cui, X. L.
Liu, G. F.
Yu, M.
JOURNAL OF COORDINATION CHEMISTRY, 2006, 59 (12) : 1361 - 1370
[47] Synthesis and Characterization of Some New Chalcones and Their Ti(III) and V(III) Complexes
Gangwar, Anuj Kumar
Chaudhary, Ritu Rani
Garg, Poonam
ASIAN JOURNAL OF CHEMISTRY, 2010, 22 (10) : 7473 - 7478
[48] SYNTHESIS OF COBALT(III) CAGE COMPLEXES - A TWIST ON AN OLD THEME IN THE INORGANIC LABORATORY
GAHAN, LR
HEALY, PC
PATCH, GJ
JOURNAL OF CHEMICAL EDUCATION, 1989, 66 (05) : 445 - 446
[49] ACYLPEROXO-IRON(III) PORPHYRIN COMPLEXES - A NEW ENTRY OF POTENT OXIDANTS FOR THE ALKENE EPOXIDATION
MACHII, K
WATANABE, Y
MORISHIMA, I
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (25) : 6691 - 6697
[50] Synthesis, characterization and cytotoxicity evaluation of new cerium(III), lanthanum(III) and neodymium(III) complexes
Kostova, I.
Momekov, G.
APPLIED ORGANOMETALLIC CHEMISTRY, 2007, 21 (04) : 226 - 233

← 1 2 3 4 5 →