Synthesis of lutetium(III)-porphyrin complexes: old problems and new excellent conditions found

被引：2

作者：

Kalota, Bartosz ^{[1
]}

Mikus, Agnieszka ^{[2
]}

Ostrowski, Stanislaw ^{[2
]}

机构：

[1] Jan Dlugosz Univ Czgstochowa, Inst Chem Environm Protect & Biotechnol, Al Armii Krajowej 13-15, PL-42200 Czestochowa, Poland

[2] Uniwersytet Przyrodniczo Humanistyczny Siedlcach, Inst Chem, Ul 3 Maja 54, PL-08110 Siedlce, Poland

来源：

NEW JOURNAL OF CHEMISTRY | 2016年 / 40卷 / 12期

关键词：

LANTHANIDE(III) MONOPORPHYRINATE COMPLEXES; RESONANCE DIPOLAR PROBE; PORPHYRIN COMPLEXES; NUCLEOPHILIC-SUBSTITUTION; ELECTROPHILIC NITRATION; PYRROLE UNIT; SIMPLE ROUTE; LUMINESCENCE; HYDROGEN; TETRAARYLPORPHYRINS;

D O I：

10.1039/c6nj02424f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A convenient method for the preparation of very attractive and almost unknown lutetium(III)-porphyrins was developed. Systematic investigations involving a broad spectrum of solvents (DMF, TCB, imidazole, sulfolane, and a CHCl3/MeOH mixture), as well as studies concerning the influence of temperature and the reaction time on the yield, were performed. Under the optimized experimental conditions found within the study for [5,10,15,20-tetraphenylporphyrinato]lutetium(III) chloride (sulfolane, reflux, 0.5 h; 88% yield), the synthesis of some other more complex derivatives was demonstrated.

引用

页码：9899 / 9902

页数：4

共 50 条

[31] Synthesis and Characterization of a New Proline Tailed Porphyrin and Its Metalloporphyrin Complexes
Han, Linli
Song, Shuyan
Li, Guanghua
Yu, Miao
Wang, Ying
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2016, 46 (10) : 1547 - 1551
[32] Synthesis, characterization and cytotoxicity of new Ho(III) and Er(III) complexes
Kostova, Irena
Grigorov, Petar
Balkansky, Stefan
Stefanova, Tsvetanka
INDIAN JOURNAL OF BIOTECHNOLOGY, 2011, 10 (04): : 387 - 394
[33] In vitro anticancer activity of new gold(III) porphyrin complexes in colon cancer cells
Dandash, Fatima
Leger, David Yannick
Fidanzi-Dugas, Chloe
Nasri, Soumaya
Bregier, Frederique
Granet, Robert
Karam, Walid
Diab-Assaf, Mona
Sol, Vincent
Liagre, Bertrand
JOURNAL OF INORGANIC BIOCHEMISTRY, 2017, 177 : 27 - 38
[34] Porphyrin synthesis by the ''3+1'' approach: New applications for an old methodology
Lash, TD
CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (10) : 1197 - 1200
[35] SYNTHESIS OF EARLY TRANSITION-METAL PORPHYRIN HALIDE-COMPLEXES - FIRST STRUCTURAL CHARACTERIZATION OF A VANADIUM(III) PORPHYRIN COMPLEX
BERREAU, LM
HAYS, JA
YOUNG, VG
WOO, LK
INORGANIC CHEMISTRY, 1994, 33 (01) : 105 - 108
[36] Porphyrin-appended europium(III) bis(phthalocyaninato) complexes: Synthesis, characterization, and photophysical properties
Bian, Yongzhong
Chen, Xinghai
Wang, Dongying
Choi, Chi-Fung
Zhou, Yang
Zhu, Peihua
Ng, Dennis K. P.
Jiang, Jianzhuang
Weng, Yuxiang
Li, Xiyou
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (15) : 4169 - 4177
[37] Synthesis and characterization of low-spin bis(amino ester) iron(III) porphyrin complexes
Morice, C
Le Maux, P
Simonneaux, G
INORGANIC CHEMISTRY, 1998, 37 (23) : 6100 - 6103
[38] Synthesis and characterization of chromium(III) octaphenylporphyrin complexes with various axial ligands: An insight into porphyrin distortion
Harada, R
Matsuda, Y
Okawa, H
Miyamoto, R
Yamauchi, S
Kojima, T
INORGANICA CHIMICA ACTA, 2005, 358 (08) : 2489 - 2500
[39] Synthesis of polyaminosiloxane matrices with coordinated cobalt(II) and iron(III) complexes with porphyrin and phthalocyanine derivatives
Yakubovich, TN
Teslenko, VV
Veisov, BK
Zub, YL
Parish, RV
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2001, 27 (08) : 560 - 566
[40] Synthesis of Polyaminosiloxane Matrices with Coordinated Cobalt(II) and Iron(III) Complexes with Porphyrin and Phthalocyanine Derivatives
T. N. Yakubovich
V. V. Teslenko
B. K. Veisov
Yu. L. Zub
R. V. Parish
Russian Journal of Coordination Chemistry, 2001, 27 : 560 - 566

← 1 2 3 4 5 →