Synthesis of lutetium(III)-porphyrin complexes: old problems and new excellent conditions found

被引：2

作者：

Kalota, Bartosz ^{[1
]}

Mikus, Agnieszka ^{[2
]}

Ostrowski, Stanislaw ^{[2
]}

机构：

[1] Jan Dlugosz Univ Czgstochowa, Inst Chem Environm Protect & Biotechnol, Al Armii Krajowej 13-15, PL-42200 Czestochowa, Poland

[2] Uniwersytet Przyrodniczo Humanistyczny Siedlcach, Inst Chem, Ul 3 Maja 54, PL-08110 Siedlce, Poland

来源：

NEW JOURNAL OF CHEMISTRY | 2016年 / 40卷 / 12期

关键词：

LANTHANIDE(III) MONOPORPHYRINATE COMPLEXES; RESONANCE DIPOLAR PROBE; PORPHYRIN COMPLEXES; NUCLEOPHILIC-SUBSTITUTION; ELECTROPHILIC NITRATION; PYRROLE UNIT; SIMPLE ROUTE; LUMINESCENCE; HYDROGEN; TETRAARYLPORPHYRINS;

D O I：

10.1039/c6nj02424f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A convenient method for the preparation of very attractive and almost unknown lutetium(III)-porphyrins was developed. Systematic investigations involving a broad spectrum of solvents (DMF, TCB, imidazole, sulfolane, and a CHCl3/MeOH mixture), as well as studies concerning the influence of temperature and the reaction time on the yield, were performed. Under the optimized experimental conditions found within the study for [5,10,15,20-tetraphenylporphyrinato]lutetium(III) chloride (sulfolane, reflux, 0.5 h; 88% yield), the synthesis of some other more complex derivatives was demonstrated.

引用

页码：9899 / 9902

页数：4

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