Silica encapsulation of hydrophobically ligated PbSe nanocrystals

被引：49
作者：
Darbandi, M
Lu, WG
Fang, JY
Nann, T
机构：
[1] Univ Freiburg, Freiburg Mat Res Ctr, D-79104 Freiburg, Germany
[2] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA
[3] Univ New Orleans, Adv Mat Res Inst, New Orleans, LA 70148 USA
来源：
LANGMUIR | 2006年 / 22卷 / 09期
关键词：
D O I：
10.1021/la0529658
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Spherical PbSe@SiO2 nanoparticles have been successfully synthesized within reverse micelles via metal alkoxide hydrolysis and condensation within a microemulsion system. These core-shell nanoparticles were characterized by transmission electron microscopy (TEM), NIR absorption spectroscopy, energy-dispersive X-ray analysis, and TEM electron diffractions. It shows that the obtained core-shell structures have a spherical shape with narrow size distribution (average size approximately 35 nm) and smooth surfaces. The size of the particles and the thickness of the shells can be controlled by manipulating the relative rates of the hydrolysis and condensation reactions of tetraethoxysilane (TEOS) within the microemulsion.
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收藏
页码：4371 / 4375
页数：5
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