Highly efficient and stable peracid for rapid and selective oxidation of aliphatic amines to oximes

被引：15
|
作者：
Patil, Vilas V. [1 ]
Gayakwad, Eknath M. [1 ]
Shankarling, Ganapati S. [1 ]
机构：
[1] Inst Chem Technol, Dept Dyestuff Technol, Bombay 400019, Maharashtra, India
来源：
NEW JOURNAL OF CHEMISTRY | 2015年 / 39卷 / 08期
关键词：
ONE-POT CONVERSION; CATALYZED CONVERSION; MICROWAVE IRRADIATION; AEROBIC OXIDATION; NITRO-COMPOUNDS; ALDOXIMES; AMIDES; REARRANGEMENT; NITRILES; ALCOHOLS;
D O I：
10.1039/c5nj00801h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel, transition-metal free, rapid approach for selective oxidation of aliphatic and benzylic amines to oximes is described. The dodecanebis(peroxoic acid)-DMF combination efficiently oxidizes various aliphatic amines at 50 degrees C temperature to give 100% conversion in 20 min with high oxime selectivity. The peroxy acid used here shows exceptional stability at room temperature and is non-shock sensitive in nature, which was confirmed by differential scanning colorimetric (DSC) analysis.
引用
收藏
页码：6677 / 6682
页数：6
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