Highly efficient and stable peracid for rapid and selective oxidation of aliphatic amines to oximes

被引：15

作者：

Patil, Vilas V. ^{[1
]}

Gayakwad, Eknath M. ^{[1
]}

Shankarling, Ganapati S. ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Dyestuff Technol, Bombay 400019, Maharashtra, India

来源：

NEW JOURNAL OF CHEMISTRY | 2015年 / 39卷 / 08期

关键词：

ONE-POT CONVERSION; CATALYZED CONVERSION; MICROWAVE IRRADIATION; AEROBIC OXIDATION; NITRO-COMPOUNDS; ALDOXIMES; AMIDES; REARRANGEMENT; NITRILES; ALCOHOLS;

D O I：

10.1039/c5nj00801h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel, transition-metal free, rapid approach for selective oxidation of aliphatic and benzylic amines to oximes is described. The dodecanebis(peroxoic acid)-DMF combination efficiently oxidizes various aliphatic amines at 50 degrees C temperature to give 100% conversion in 20 min with high oxime selectivity. The peroxy acid used here shows exceptional stability at room temperature and is non-shock sensitive in nature, which was confirmed by differential scanning colorimetric (DSC) analysis.

引用

页码：6677 / 6682

页数：6

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