Crystal and molecular structure of zinc(II) di-n-propyldithiocarbamate complexes with 2,2′-bipyridyl and 1,10-phenanthroline

被引:2
|
作者
Glinskaya, LA [1 ]
Klevtsova, RF
Berus, EI
Zemskova, SM
Larionov, SV
机构
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
关键词
Phen; Bipy; Bipyridyl; Crystal Structure Analysis; Nmeas;
D O I
10.1007/BF02903631
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The structure of Zn[S2CN(n-C3H7)(2)](2)(2,2'-Bipy) and Zn[S2CN(n-C3H7)(2)](2)Phen was determined by X-ray diffraction analysis (CAD-4 diffractometer, MoKalpha radiation) for the monoclinic (a = 9.646, b = 20.978, c = 14.555 Angstrom; beta = 94.95 degrees; Z = 4;space group P2(1)/n) and orthorhombic (a = 18.621, b = 14.701, c = 10.676 Angstrom; Z = 4; space group Aba2) crystals. The structures consist of discrete monomer molecules packed with the aid of S ... H-C and C ... H-C hydrogen bonds and van der Waals interactions.
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页码:559 / 566
页数:8
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