Activated carbon nanocomposite electrodes for high performance supercapacitors

被引:42
作者
Jang, Yunseok [1 ]
Jo, Jeongdai [1 ]
Choi, Young-Man [1 ]
Kim, Inyoung [1 ]
Lee, Seung-Hyun [1 ]
Kim, Daewon [1 ]
Yoon, Seong Man [1 ]
机构
[1] Korea Inst Machinery & Mat, Dept Printed Elect, Taejon 305343, South Korea
关键词
Supercapacitors; Functionalized activated carbon; Nanocomposite; Spray coating; Cross-linkable polymeric binder; HIGH-POWER; ENERGY DENSITY;
D O I
10.1016/j.electacta.2013.04.020
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Supercapacitors with high capacitance, high energy density and a small time constant have been developed successfully using functionalized activated carbon nanoparticles (FACNs) and a cross-linkable polymeric binder in neutral aqueous Na2SO4. Due to the functional groups on the FACNs' surface and the slenderness of the FACNs' nanocomposite electrode, the FACNs' nanocomposite electrode exhibits superior specific capacitance of 154 F/g, energy density of 18 Wh/kg, and a time constant of 0.25 s. Furthermore, the cyclic voltammogram is still rectangular in shape even at exceedingly high scan rates of 5 V/s. These characteristics show that our proposed method is suitable for the fabrication of high-performance supercapacitors. (c) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:240 / 245
页数:6
相关论文
共 22 条
[1]  
An KH, 2001, ADV FUNCT MATER, V11, P387, DOI 10.1002/1616-3028(200110)11:5<387::AID-ADFM387>3.0.CO
[2]  
2-G
[3]   Cyclic voltammetric and FTIR studies of powdered carbon electrodes in the electrosorption of 4-chlorophenols from aqueous electrolytes [J].
Biniak, S. ;
Swiatkowski, A. ;
Pakula, M. ;
Sankowska, M. ;
Kusmierek, K. ;
Trykowski, G. .
CARBON, 2013, 51 :301-312
[4]   Asymmetric Supercapacitors Based on Graphene/MnO2 and Activated Carbon Nanofiber Electrodes with High Power and Energy Density [J].
Fan, Zhuangjun ;
Yan, Jun ;
Wei, Tong ;
Zhi, Linjie ;
Ning, Guoqing ;
Li, Tianyou ;
Wei, Fei .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (12) :2366-2375
[5]   Impedance characteristics of the nanoporous honeycomb diamond electrodes for electrical double-layer capacitor applications [J].
Honda, K ;
Rao, TN ;
Tryk, DA ;
Fujishima, A ;
Watanabe, M ;
Yasui, K ;
Masuda, H .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (07) :A668-A679
[6]   Patterning the organic electrodes of all-organic thin film transistors with a simple spray printing technique [J].
Jang, Yunseok ;
Park, Yeong Don ;
Lim, Jung Ah ;
Lee, Hwa Sung ;
Lee, Wi Hyoung ;
Cho, Kilwon .
APPLIED PHYSICS LETTERS, 2006, 89 (18)
[7]   Principles and applications of electrochemical capacitors [J].
Kötz, R ;
Carlen, M .
ELECTROCHIMICA ACTA, 2000, 45 (15-16) :2483-2498
[8]   Immobilization of high catalytic acid protease on functionalized mesoporous activated carbon particles [J].
Kumar, A. Ganesh ;
Swarnalatha, S. ;
Kamatchi, P. ;
Sekaran, G. .
BIOCHEMICAL ENGINEERING JOURNAL, 2009, 43 (02) :185-190
[9]   WO3-x@Au@MnO2 Core-Shell Nanowires on Carbon Fabric for High-Performance Flexible Supercapacitors [J].
Lu, Xihong ;
Zhai, Teng ;
Zhang, Xianghui ;
Shen, Yongqi ;
Yuan, Longyan ;
Hu, Bin ;
Gong, Li ;
Chen, Jian ;
Gao, Yihua ;
Zhou, Jun ;
Tong, Yexiang ;
Wang, Zhong Lin .
ADVANCED MATERIALS, 2012, 24 (07) :938-+
[10]   Performance improvement of Nafion based solid state electrochemical supercapacitor [J].
Lufrano, F ;
Staiti, P .
ELECTROCHIMICA ACTA, 2004, 49 (16) :2683-2689