Syntheses, Structures, and Catalytic Activities of Copper( I) Complexes with the Ligand 2( 4,5-Diphenyl-1H-imidazol-2-yl) pyridine

被引：1

作者：

Yang, Hua ^{[1
,2
]}

Liu, Yonglu ^{[3
]}

Hu, Dao-Dao ^{[1
]}

机构：

[1] Shaanxi Normal Univ, Sch Mat Sci & Engn, Xian 710062, Shaanxi, Peoples R China

[2] Yanan Univ, Coll Chem & Chem Engn, Yanan 716000, Shaanxi, Peoples R China

[3] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 02期

关键词：

CRYSTAL-STRUCTURES; CU(I) COMPLEXES; PHOTOPHYSICS; ELECTROCHEMISTRY; RUTHENIUM(II); REACTIVITY;

D O I：

10.1002/zaac.201300223

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two copper(I) complexes of compositions [Cu(HL)I]2·EtOH (1) and [Cu(HL)3]I·MeOH (2) were synthesized via the reactions of HL [HL = 2(4,5-diphenyl-1H-imidazol-2-yl)pyridine] and CuI in EtOH and MeOH, respectively, under solvothermal conditions. The complexes were characterized by X-ray single crystal diffraction, IR spectroscopy, and elemental analysis. Compounds 1 and 2 are catalytically active towards ketalization reaction, giving various ketals under mild conditions. Copyright © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：394 / 397

页数：4

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