Highly efficient GaAs solar cells by limiting light emission angle

被引:278
作者
Kosten, Emily D. [1 ]
Atwater, Jackson H. [2 ]
Parsons, James [2 ]
Polman, Albert [2 ]
Atwater, Harry A. [1 ]
机构
[1] CALTECH, Thomas J Watson Labs Appl Phys, Pasadena, CA 91125 USA
[2] FOM Inst AMOLF, Ctr Nanophoton, NL-1098 XG Amsterdam, Netherlands
基金
欧洲研究理事会;
关键词
detailed balance; GaAs solar cell; light trapping; photovoltaics; two photon lithography; MINORITY-CARRIER LIFETIME; RECOMBINATION;
D O I
10.1038/lsa.2013.1
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
In a conventional flat plate solar cell under direct sunlight, light is received from the solar disk, but is re-emitted isotropically. This isotropic emission corresponds to a significant entropy increase in the solar cell, with a corresponding drop in efficiency. Here, using a detailed balance model, we show that limiting the emission angle of a high-quality GaAs solar cell is a feasible route to achieving power conversion efficiencies above 38% with a single junction. The highest efficiencies are predicted for a thin, light trapping cell with an ideal back reflector, though the scheme is robust to a non-ideal back reflector. Comparison with a conventional planar cell geometry illustrates that limiting emission angle in a light trapping geometry not only allows for much thinner cells, but also for significantly higher overall efficiencies with an excellent rear reflector. Finally, we present ray-tracing and detailed balance analysis of two angular coupler designs, show that significant efficiency improvements are possible with these couplers, and demonstrate initial fabrication of one coupler design.
引用
收藏
页码:e45 / e45
页数:6
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