Syntheses and structures of transition metal complexes with dithiophosphinato and trithiophosphinato ligands

被引：8
作者：
Shafaei-Fallah, Maryam
Shi, Weifeng
Fenske, Dieter
Rothenberger, Alexander
机构：
[1] Univ Karlsruhe, Inst Anorgan Chem, D-76131 Karlsruhe, Germany
[2] Forschungszentrum Karlsruhe GmbH, Inst Nanotechnol, Karlsruhe, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2006年 / 632卷 / 06期
关键词：
manganese; nickel; cobalt; P ligands; S ligands; crystal structures;
D O I：
10.1002/zaac.200600023
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of MnCl2 with Ph(2)p(S)(SSiMe3) produced [Mn(S2PPh2)(2)(thf)(2)] (1) and [Mn(S2PPh2)(2)(dme)] (2) (DME = 1,2-Dimethoxyethane). The compounds [Co-6(S3PPh)(2)(mu(4)-S)(2)(mu(3)-S)(2)(PPh3)(4)] (3), [Co-2(S3PPh)(2)(PPh3)(2)] (4), [Ni(S2PPh)(PPhEt2)(2)] (5), [Ni(S3PPh)(PPhEt2)(2)] (6) and [Cu-4(S3PPh)(2)(dppp)(2)] (8) [dppp = 1,3-Bis(diplenylphosphanyl)propane] were obtained from reactions of first-row transition metal halides with PhP(S)(SSiMe3)(2) in the presence of tertiary phosphines. In a reaction of PhP(S)(SSiMe3)(2) with PhPEt2 PhPEt2PS2Ph (7) was isolated. All compounds were characterized by X-ray crystallography.
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页码：1091 / 1096
页数：6
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