Fluoroalkyl-containing phosphines

被引：20

作者：

Brisdon, Alan K. ^{[1
]}

Herbert, Christopher J. ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

COORDINATION CHEMISTRY REVIEWS | 2013年 / 257卷 / 5-6期

关键词：

Review; Phosphines; Fluoroalkyl; Transition metal complexes; Catalysis; Spectroscopic data; NUCLEAR-MAGNETIC-RESONANCE; P-DONOR LIGANDS; COORDINATION CHEMISTRY; REACTIVITY PROPERTIES; (FLUOROALKYL)PHOSPHINE COMPLEXES; ORGANOPHOSPHORUS CHEMISTRY; TRIFLUOROMETHYL GROUP; ELECTROPHILIC TRIFLUOROMETHYLATION; ORGANOMETALLIC CHEMISTRY; PHOSPHORUS(III) LIGANDS;

D O I：

10.1016/j.ccr.2012.07.028

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review describes recent advances in the synthesis, chemistry and applications of phosphine ligands containing one or more perfluoroalkyl, R-f, substituent. The methods reviewed are capable of generating a wide variety of monodentate, bidentate and PCP-pincer ligands containing R-f groups. Based on the chemistry of complexes containing these ligands, and compilations of their spectroscopic data and structural parameters it is shown that fluoroalkyl-containing phosphines have a distinct combination of steric and electronic properties, often quite different to fluoroaryl analogues. The catalytic activities displayed by complexes of these ligands are described. (c) 2012 Elsevier B.V. All rights reserved.

引用

页码：880 / 901

页数：22

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