Catalysis of the oxidation of triphenylphosphine and of trimethyl phosphite by hydrogen peroxide in the presence of Fe-III compounds

被引：8
|
作者：
Barton, DHR
Hill, DR
Hu, B
机构：
[1] Department of Chemistry, Texas A and M University, College Station
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 10期
关键词：
D O I：
10.1016/S0040-4039(97)00177-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The oxidation of triphenylphosphine to the corresponding oxide in pyridine is faster in the presence of Fe-III compounds, especially FeCl3. Even greater effects are seen for the oxidation of trimethyl phosphite. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：1711 / 1712
页数：2
相关论文
共 50 条
  • [1] OXIDATION OF TRIPHENYLPHOSPHINE WITH HYDROGEN PEROXIDE
    COPLEY, DB
    MILLER, JR
    THOMPSON, A
    FAIRBROTHER, F
    PROCEEDINGS OF THE CHEMICAL SOCIETY OF LONDON, 1964, (SEP): : 300 - &
  • [2] Hydrogen Peroxide Decomposition by Pyrite in the Presence of Fe(III)-ligands
    Chirita, P.
    CHEMICAL AND BIOCHEMICAL ENGINEERING QUARTERLY, 2009, 23 (03) : 259 - 265
  • [3] Autocatalytic oxidation of nitrobenzene using hydrogen peroxide and Fe(III)
    Nichela, Daniela
    Carolos, Luciano
    Garcia Einschlag, Fernando
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 82 (1-2) : 11 - 18
  • [4] OXIDATION OF PHOSPHORUS HYDRIDE BY HYDROGEN-PEROXIDE IN PRESENCE OF FE(III) BROMIDE AND LITHIUM-CHLORIDE
    SOKOLSKII, DV
    DORFMAN, YA
    RAKITSKAYA, TL
    SAPOVA, RG
    ZHURNAL FIZICHESKOI KHIMII, 1974, 48 (11): : 2758 - 2761
  • [5] Co-catalysis of trace dissolved Fe(iii) with biochar in hydrogen peroxide activation for enhanced oxidation of pollutants
    Feng, Dongqing
    Shou, Jianxin
    Guo, Sen
    Ya, Mengna
    Li, Jianfa
    Dong, Huaping
    Li, Yimin
    RSC ADVANCES, 2022, 12 (27) : 17237 - 17248
  • [6] Hydrogen Peroxide Oxidation of Phosphite Triesters in Oligonucleotide Syntheses
    Cvetovich, Raymond J.
    ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2010, 14 (01) : 295 - 297
  • [7] THE OXIDATION OF ASCORBIC ACID BY HYDROGEN PEROXIDE - CATALYSIS BY ETHYLENEDIAMINETETRAACETATO-IRON(III)
    GRINSTEAD, RR
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (13) : 3464 - 3471
  • [8] KINETICS AND MECHANISM OF OXIDATION OF TRIPHENYLPHOSPHINE BY HYDROGEN-PEROXIDE
    CHELLAMANI, A
    SURESH, R
    REACTION KINETICS AND CATALYSIS LETTERS, 1988, 37 (02): : 501 - 505
  • [9] Oxidation of organic sulfur compounds with hydrogen peroxide in the presence of crown ethers
    Anisimov, A. V.
    Tarakanova, A. V.
    Tkhai, Fat Vin
    Kulikov, I. S.
    Seleznev, A. A.
    PETROLEUM CHEMISTRY, 2007, 47 (03) : 225 - 225
  • [10] Oxidation of Organic Sulfur Compounds with Hydrogen Peroxide in the Presence of Crown Ethers
    Anisimov, A. V.
    Pham Vinh Thau
    Tarakanova, A. V.
    Seleznev, A. A.
    Chertkov, V. A.
    Rakhmanov, E. V.
    Kulikov, N. S.
    MOSCOW UNIVERSITY CHEMISTRY BULLETIN, 2008, 63 (01) : 48 - 54
12345