A face-capped [Fe4L4]8+ spin crossover tetrahedral cage

被引：91

作者：

Ferguson, Alan ^{[1
]}

Squire, Marie A. ^{[1
]}

Siretanu, Diana ^{[2
,3
]}

Mitcov, Dmitri ^{[2
,3
]}

Mathoniere, Corine ^{[4
,5
]}

Clerac, Rodolphe ^{[2
,3
]}

Kruger, Paul E. ^{[1
]}

机构：

[1] Univ Canterbury, Dept Chem, Christchurch 8041, New Zealand

[2] CNRS, Ctr Rech Paul Pascal, UPR 8641, F-33600 Pessac, France

[3] Univ Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France

[4] CNRS, ICMCB, UPR 9048, F-33600 Pessac, France

[5] Univ Bordeaux, ICMCB, UPR 9048, F-33600 Pessac, France

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 16期

关键词：

FRAMEWORK MATERIAL; ANION-BINDING; TRANSITION; COMPLEXES; BEHAVIOR; CATALYSIS; HELICATE; LIGHT; HOSTS;

D O I：

10.1039/c3cc00012e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reported here is a face-capped Fe(II) molecular tetrahedron, [Fe4L4](BF4)(8), 1. Single crystal X-ray diffraction at 153 and 293 K suggest spin crossover (SCO) and variable temperature magnetic susceptibility measurements confirm 1 displays thermally driven SCO behaviour in the solid state and in dilute acetone solution centred around 284-288 K.

引用

页码：1597 / 1599

页数：3

共 37 条

[1] SELF-ASSEMBLY OF A FERROMAGNETICALLY COUPLED MANGANESE(II) TETRAMER [J].

AMOROSO, AJ ;

JEFFERY, JC ;

JONES, PL ;

MCCLEVERTY, JA ;

THORNTON, P ;

WARD, MD .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (13-14) :1443-1446

[2] Partial spin crossover behaviour in a dinuclear iron(II) triple helicate [J].

Archer, Rosanna J. ;

Hawes, Chris S. ;

Jameson, Guy N. L. ;

Mckee, Vickie ;

Moubaraki, Boujemaa ;

Chilton, Nicholas F. ;

Murray, Keith S. ;

Schmitt, Wolfgang ;

Kruger, Paul E. .

DALTON TRANSACTIONS, 2011, 40 (45) :12368-12373

[3]

Atkins P., 2006, PHYS CHEM

[4] Subcomponent Self-Assembly and Guest-Binding Properties of Face-Capped Fe4L48+ Capsules [J].

Bilbeisi, Rana A. ;

Clegg, Jack K. ;

Elgrishi, Noemie ;

de Hatten, Xavier ;

Devillard, Marc ;

Breiner, Boris ;

Mal, Prasenjit ;

Nitschke, Jonathan R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (11) :5110-5119

[5]

Breuning E, 2000, ANGEW CHEM INT EDIT, V39, P2504, DOI 10.1002/1521-3773(20000717)39:14<2504::AID-ANIE2504>3.0.CO

[6]

2-B

[7] An expanded neutral M4L6 cage that encapsulates four tetrahydrofuran molecules [J].

Clegg, Jack K. ;

Li, Feng ;

Jolliffe, Katrina A. ;

Meehan, George V. ;

Lindoy, Leonard F. .

CHEMICAL COMMUNICATIONS, 2011, 47 (21) :6042-6044

[8] MOLECULAR CONTAINER COMPOUNDS [J].

CRAM, DJ .

NATURE, 1992, 356 (6364) :29-36

[9] Metallo-supramolecular capsules [J].

Dalgarno, Scott J. ;

Power, Nicholas P. ;

Atwood, Jerry L. .

COORDINATION CHEMISTRY REVIEWS, 2008, 252 (8-9) :825-841

[10] A Nanoscale Molecular Switch Triggered by Thermal, Light, and Guest Perturbation [J].

Duriska, Martin B. ;

Neville, Suzanne M. ;

Moubaraki, Boujemaa ;

Cashion, John A. ;

Halder, Gregory J. ;

Chapman, Karena W. ;

Balde, Cherif ;

Letard, Jean-Francois ;

Murray, Keith S. ;

Kepert, Cameron J. ;

Batten, Stuart R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (14) :2549-2552

← 1 2 3 4 →