Analysis of biomass and sewage sludge devolatilization using the distributed activation energy model

被引:85
作者
Soria-Verdugo, A. [1 ]
Garcia-Hernando, N. [1 ]
Garcia-Gutierrez, L. M. [1 ]
Ruiz-Rivas, U. [1 ]
机构
[1] Univ Carlos III Madrid, Energy Syst Engn Grp, Thermal & Fluids Engn Dept, Madrid 28911, Spain
关键词
DAEM; Biomass devolatilization; Pyrolysis kinetics; Sewage sludge; KINETIC-PARAMETERS; PYROLYSIS; WOOD; GASIFICATION; COMBUSTION; EVOLUTION; PRODUCTS; BEHAVIOR; COAL;
D O I
10.1016/j.enconman.2012.08.017
中图分类号
O414.1 [热力学];
学科分类号
摘要
The thermal decomposition of biomass (pine pellets) and sewage sludge was studied using thermogravimetric analysis under an inert atmosphere and the Distributed Activation Energy Model (DAEM) was employed. The activation energy and the frequency factor that characterize the kinetics were determined for both samples. A simplification of the process for prediction of devolatilization curves was proposed, evaluating its validity for both cases. The simplified method was found to combine both simplicity and low deviations with experimental data. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:239 / 244
页数:6
相关论文
共 31 条
[1]   Jute stick pyrolysis for bio-oil production in fluidized bed reactor [J].
Asadullah, M. ;
Rahman, M. Anisur ;
Ali, M. Mohsin ;
Motin, M. Abdul ;
Sultan, M. Borhanus ;
Alam, M. Robiul ;
Rahman, M. Sahedur .
BIORESOURCE TECHNOLOGY, 2008, 99 (01) :44-50
[2]   Devolatilization rate of biomasses and coal-biomass blends: an experimental investigation [J].
Biagini, E ;
Lippi, F ;
Petarca, L ;
Tognotti, L .
FUEL, 2002, 81 (08) :1041-1050
[3]   New distributed activation energy model: Numerical solution and application to pyrolysis kinetics of some types of biomass [J].
Cai, Junmeng ;
Liu, Ronghou .
BIORESOURCE TECHNOLOGY, 2008, 99 (08) :2795-2799
[4]   KINETIC PARAMETERS FROM THERMOGRAVIMETRIC DATA [J].
COATS, AW ;
REDFERN, JP .
NATURE, 1964, 201 (491) :68-&
[5]   Pyrolytic behavior and products of some wood varieties [J].
Di Blasi, C ;
Branca, C ;
Santoro, A ;
Hernandez, EG .
COMBUSTION AND FLAME, 2001, 124 (1-2) :165-177
[6]   Distributed activation energy model parameters of some Turkish coals [J].
Gunes, M. ;
Gunes, S. K. .
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2008, 30 (16) :1460-1472
[7]   Kinetic study of Chinese biomass slow pyrolysis: Comparison of different kinetic models [J].
Hu, Song ;
Jess, Andreas ;
Xu, Minhou .
FUEL, 2007, 86 (17-18) :2778-2788
[8]   Potential of synthesis gas production from rubber wood chip gasification in a bubbling fluidised bed gasifier [J].
Kaewluan, Sommas ;
Pipatmanomai, Suneerat .
ENERGY CONVERSION AND MANAGEMENT, 2011, 52 (01) :75-84
[9]   Experimental investigation of ash behavior and emissions during combustion of Bosnian coal and biomass [J].
Kazagic, A. ;
Smajevic, I. .
ENERGY, 2007, 32 (10) :2006-2016
[10]   IMPLICATIONS OF MULTIPLICITY IN KINETIC-PARAMETERS TO PETROLEUM-EXPLORATION - DISTRIBUTED ACTIVATION-ENERGY MODELS [J].
LAKSHMANAN, CC ;
BENNETT, ML ;
WHITE, N .
ENERGY & FUELS, 1991, 5 (01) :110-117