To Study the Effect of LiMn2O4, Nanofibers of LiMn2O4, and Graphene/Polyaniline/Carbon Nanotube as Electrode Materials in the Fuel Cell

被引:14
作者
Ali, Kabbir [1 ]
Raza, Hafiz Ali [1 ]
Malik, Muhammad Irfan [2 ]
Ibn Shamsah, Sami [3 ]
Amna, Riffat [4 ]
Sarfraz, Amina [5 ]
机构
[1] Chonnam Natl Univ, Dept Mech Design Engn, Yeosu 550749, South Korea
[2] Univ Hafr Al Batin, Dept Chem Engn, Coll Engn, POB 1803, Hafar al Batin 31991, Saudi Arabia
[3] Univ Hafr Al Batin, Dept Mech Engn, Coll Engn, POB 1803, Hafar al Batin 31991, Saudi Arabia
[4] Khalifa Univ, Dept Chem Engn, Abu Dhabi, U Arab Emirates
[5] COMSATS Inst Informat Technol, Lahore, Pakistan
关键词
perovskite LiMn2O4; graphene/polyaniline/carbon nanotube; Fuel cell; Solid oxide fuel cell (SOFC); oxygen reduction reactions (ORR); OXYGEN-TRANSPORT; CATHODE MATERIAL; HYDROCARBONS; OXIDATION;
D O I
10.14447/jnmes.v23i1.a01
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This study is conducted to explore the best electrodes materials for energy conversion devices. The two cathode materials (LiMn2O4 and nanofibers of LiMn2O4) and the anode material (graphene/polyaniline/carbon-nanotube) were synthesized by a wet chemical method which includes sol-gel and chemical polymerization techniques. The prepared materials were characterized by SEM, XRD FTIR, and cyclic voltammetry. The characterization results show that LiMn2O4 exhibits a porous and hollow structure, which improves the utilization of the active mass area, and allows the dual conduction of Li+ and electrons, which effectively relieves the structural strain and volume change The cyclic voltammetry results record that LiMn2O4 and nanofibers of LiMn2O4 as a cathode material enhanced the cycling performance and possess excellent stability. Further, the conductivity of each sample was measured using the DC four-probe method, and the highest conductivity was observed for the LiMn2O4 nanofibers 1.43 SCm-1 at 650 degrees C.
引用
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页码:1 / 6
页数:6
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