Spectral Studies on Pt(II) and Pd(II) Complexes with N-benzoyl-N′-aryl Thiourea derivatives

被引：0
|
作者：
Circu, Viorel [1 ]
Rosu, Tudor [1 ]
Udrea, Silvia [2 ]
Dumitrascu, Florea [2 ]
机构：
[1] Univ Bucharest, Dept Inorgan Chem, Bucharest 020464, Romania
[2] Romanian Acad, Ctr Organ Chem CD Nenitzescu, Bucharest 060023, Romania
来源：
REVISTA DE CHIMIE | 2008年 / 59卷 / 08期
关键词：
Pt(II) and Pd(II) complexes; N-benzoyl-N '-aryl thiourea; IR and UV-VIS; H-1 and C-13 NMR spectroscopy;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of Pt(II) and Pd(II) complexes with N-benzoyl-N '-aryl thiourea derivatives were prepared and investigated by mean of several spectroscopic techniques: IR and UV-VIS, H-1 and C-13 NMR spectroscopy. These derivatives act as monodentote ligands through the sulphur atom to Pt(II) and as bidentate through the sulphur and oxygen atoms to Pd(II). The 1H NMR spectroscopy shows the presence of a mixture of cis and trans isomers in solution for both Pt(II) and Pd(II) complexes.
引用
收藏
页码：934 / 938
页数：5
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