Synthesis of Biobased Long-Chain Polyesters by Acyclic Diene Metathesis Polymerization and Tandem Hydrogenation and Depolymerization with Ethylene

被引：25
|
作者：
Nomura, Kotohiro [1 ]
Chaijaroen, Permpoon [1 ]
Abdellatif, Mohamed Mehawed [1 ]
机构：
[1] Tokyo Metropolitan Univ, Grad Sch Sci, Dept Chem, Hachioji, Tokyo 1920397, Japan
来源：
ACS OMEGA | 2020年 / 5卷 / 29期
关键词：
TRANSFER RADICAL POLYMERIZATION; RENEWABLE RESOURCES; BRANCHED POLYETHYLENE; ADMET POLYMERIZATION; MOLECULAR-WEIGHT; SEMICRYSTALLINE POLYESTERS; ALIPHATIC POLYESTERS; OLEFIN ISOMERIZATION; CASTOR-OIL; POLYMERS;
D O I：
10.1021/acsomega.0c01965
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Acyclic diene metathesis (ADMET) polymerization of biobased alpha,omega-dienes of bis(undec-10-enoate) with diols (1,4-butanediol, isosorbide, isomannide, and 1,4-cyclohexanedimethanol) afforded high-molecular weight unsaturated polyesters, and subsequent tandem hydrogenation (H-2 1.0 MPa, 50 degrees C, 3 h) gave the saturated polymers upon addition of a small amount of Al2O3 (1.0-1.7 wt %). Subsequent reaction of the unsaturated polymers with ethylene afforded the oligomers (by depolymerization and degradation).
引用
收藏
页码：18301 / 18312
页数：12
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