Poly(1,2-propylene glycol adipate) as an Environmentally Friendly Plasticizer for Poly(vinyl chloride)

被引：8

作者：

Zhao, Yan ^{[1
,2
]}

Liang, Hongyu ^{[1
,2
]}

Wu, Dandan ^{[1
,2
]}

Bian, Junjia ^{[1
]}

Hao, Yanping ^{[1
,3
]}

Zhang, Guibao ^{[1
]}

Liu, Sanrong ^{[1
]}

Zhang, Huiliang ^{[1
]}

Dong, Lisong ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Polymer Ecomat, Beijing 100864, Peoples R China

[2] Changchun Univ Technol, Coll Chem Engn, Changchun, Jilin, Peoples R China

[3] Jilin Univ, Coll Chem, Changchun, Jilin, Peoples R China

来源：

POLYMER-KOREA | 2015年 / 39卷 / 02期

基金：

美国国家科学基金会; 国家高技术研究发展计划(863计划);

关键词：

poly(vinyl chloride); poly(1,2-propylene glycol adipate); plasticizer; blends; mechanical properties; MECHANICAL-PROPERTIES; MIGRATION; PVC;

D O I：

10.7317/pk.2015.39.2.247

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(1,2-propylene glycol adipate) (PPA) was used as an environmentally friendly plasticizer in flexible poly(vinyl chloride) (PVC). Thermal, mechanical, and rheological properties of the PVC/PPA blends were characterized by differential scanning calorimetry, dynamic mechanical analysis, tensile test, scanning electron microscopy and small amplitude oscillatory shear rheometry. The results showed that PPA lowered the glass transition temperature of PVC. The introduction of PPA could decrease tensile strength and Young's modulus of the PVC/PPA blends; however, elongation-at-break was dramatically increased due to the plastic deformation. The plasticization effect of PPA was also manifested by the decrease of dynamic storage modulus and viscosity in the melt state of the blends. The results indicated that PPA had a good plasticizing effect on PVC.

引用

页码：247 / 255

页数：9

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