Synthesis, crystal structure and spectroscopic properties of a new chiral cadmium (II) malate

被引：9

作者：

Beghidja, Adel ^{[1
,2
]}

Beghidja, Chahrazed ^{[2
,3
]}

Rogez, Guillaume ^{[1
]}

Rabu, Pierre ^{[1
]}

Welter, Richard ^{[3
]}

机构：

[1] ULP, CNRS,UMR 7504, Inst Phys & Chim Mat Strasbourg, Grp Mat Inorgan, F-67034 Strasbourg 2, France

[2] Univ Mentouri Constantine, Lab Chim Mol Controle Environm & Mesures Physicoc, Constantine, Algeria

[3] Univ Strasbourg 1, CNRS, UMR 7177, Lab DECOMET, F-67000 Strasbourg, France

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 09期

关键词：

malate ligands; coordination polymer; chirality; cadmium; hydrothermal synthesis;

D O I：

10.1016/j.inoche.2008.06.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new chiral 3D metal-organic coordination polymer [Cd((S)-mal)] (mal = malic acid), has been solvothermally synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. Colorless crystals crystallize in the orthorhombic system, space group P2(1)2(1)2(1), a = 6.804(1), b = 8.488(2), c = 9.997(3) angstrom, V = 577.35 (2) angstrom(3), Z = 4 and R-1 = 0.0298. The structure of the compound exhibits a chiral 3D covalent framework based on chiral bridging ligands, the coordination environment around the Cd-II is pentagonal bipyramidal. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1088 / 1090

页数：3

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