Urea methanolysis to dimethyl carbonate over ZnO-CeO2-MO (MO: La2O3, Y2O3, Co2O3, Ga2O3, and ZrO2) catalysts

被引：29

作者：

Joe, Wangrae ^{[1
]}

Lee, Hye Jin ^{[1
]}

Hong, Ung Gi ^{[1
]}

Ahn, Young Soo ^{[2
]}

Song, Chan Ju ^{[2
]}

Kwon, Bum Jin ^{[2
]}

Song, In Kyu ^{[1
]}

机构：

[1] Seoul Natl Univ, Inst Chem Proc, Sch Chem & Biol Engn, Seoul 151744, South Korea

[2] S Oil Corp, Ulsan 689982, South Korea

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2012年 / 18卷 / 05期

关键词：

Dimethyl carbonate; Methanol; Urea; ZnO-CeO2-MO; Basicity; IMMOBILIZED IONIC LIQUID; GLYCEROL CARBONATE; ETHYLENE CARBONATE; OXIDE; ALCOHOLYSIS; DIOXIDE; BATTERY;

D O I：

10.1016/j.jiec.2012.03.017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of ZnO(0.64)-CeO2(0.26)-MO(0.1) (MO: La2O3, Y2O3, Co2O3, Ga2O3, and ZrO2) and ZnO(0.7)-CeO2(0.3) catalysts with a fixed molar composition (value in parenthesis) were prepared by a sol-gel method for use in the urea methanolysis to dimethyl carbonate (DMC). Effect of acidity and basicity of ZnO(0.64)-CeO2(0.26)-MO(0.1) on the catalytic performance was investigated. Experimental results revealed that basicity of the catalysts played more important role in determining the catalytic performance than acidity. Yield of DMC increased with increasing basicity of the catalyst. Among the catalysts tested, ZnO(0.64)-CeO2(0.26)-La2O3(0.1) with the largest basicity exhibited the best catalytic performance (50.4% of DMC yield). (C) 2012 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：1730 / 1735

页数：6

共 36 条

[1] CHEMISTRY OF PHOSGENE [J].

BABAD, H ;

ZEILER, AG .

CHEMICAL REVIEWS, 1973, 73 (01) :75-91

[2] Synthesis of glycerol carbonate from glycerol and dimethyl carbonate catalyzed by KF modified hydroxyapatite [J].

Bai, Rongxian ;

Wang, Shu ;

Mei, Fuming ;

Li, Tao ;

Li, Guangxing .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2011, 17 (04) :777-781

[3] CARBONATES AND POLYCARBONATES FROM UREA AND ALCOHOL [J].

BALL, P ;

FULLMANN, H ;

HEITZ, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1980, 19 (09) :718-720

[4] Synthesis of glycerol carbonate from ethylene carbonate and glycerol using immobilized ionic liquid catalysts [J].

Cho, Han-Jun ;

Kwon, Hye-Mi ;

Tharun, Jose ;

Park, Dae-Won .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2010, 16 (05) :679-683

[5] Developments in the production and application of dimethylcarbonate [J].

Delledonne, D ;

Rivetti, F ;

Romano, U .

APPLIED CATALYSIS A-GENERAL, 2001, 221 (1-2) :241-251

[6] Ni-Me-O mixed metal oxides for the effective oxidative dehydrogenation of ethane to ethylene - Effect of promoting metal Me [J].

Heracleous, E. ;

Lemonidou, A. A. .

JOURNAL OF CATALYSIS, 2010, 270 (01) :67-75

[7] Superpalite [J].

Hood, HP ;

Murdock, HR .

JOURNAL OF PHYSICAL CHEMISTRY, 1919, 23 (07) :498-512

[8] Liquid-liquid equilibria for ternary systems of dimethyl carbonate + C1-C4 alcohols + water at 298.15 K and atmospheric pressure [J].

Hwang, In-Chan ;

Park, So-Jin ;

Han, Kyu-Jin ;

In, Se-Jin .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2012, 18 (01) :499-503

[9] Dimethyl carbonate as potential reactant in non-catalytic biodiesel production by supercritical method [J].

Ilham, Zul ;

Saka, Shiro .

BIORESOURCE TECHNOLOGY, 2009, 100 (05) :1793-1796

[10] HOMOGENEOUS CATALYSIS IN SUPERCRITICAL FLUIDS [J].

JESSOP, PG ;

IKARIYA, T ;

NOYORI, R .

SCIENCE, 1995, 269 (5227) :1065-1069

← 1 2 3 4 →