Quantum Stochastic Dynamics in the Presence of a Time-Periodic Rapidly Oscillating Potential: Nonadiabatic Escape Rate

被引:8
作者
Shit, Anindita [1 ]
Chattopadhyay, Sudip [1 ]
Chaudhuri, Jyotipratim Ray [2 ]
机构
[1] Bengal Engn & Sci Univ, Dept Chem, Sibpur 711103, Howrah, India
[2] Katwa Coll, Dept Phys, Burdwan 713130, W Bengal, India
关键词
BROWNIAN-MOTION; ACTIVATED EVENTS; PHASE-SPACE; DRIVEN; NOISE; DIFFUSION; RELAXATION; EQUATIONS; TRANSPORT; KRAMERS;
D O I
10.1021/jp402565y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Escape from a metastable state in the presence of a high-frequency field (where the driving becomes nonadiabatic) underlies a broad range of phenomena of physics and chemistry, and thus its understanding is of paramount importance. We study the problem of intermediate-to-high-damping escape from a metastable state of a dissipative system driven by a rapidly oscillating field, one of the most important classes of nonequilibrium systems, in a broad range of field driving frequencies (omega) and amplitudes (a). We construct a Langevin equation using quantum gauge transformation in the light of Floquet theorem and exploiting a systematic perturbative expansion in powers of 1/omega using "Kapitza-Landau time window". The quantum dynamics in a high-frequency field are found to be described by an effective time-independent potential. The temperature dependence of escape rate and the change of its form with varying parameters of the field have been analyzed. It may decrease upon increasing the temperature which is contingent on the effects of intricate interplay between external modulation and dissipation. The crossover temperature between tunnelling and thermal hopping increases with an increase in external modulation so that quantum effects in the escape are relevant at higher temperatures. These observations are uncommon and counterintuitive and, therefore, of considerable interest. Our results might be valuable for the exploration of the dynamics of cold atoms in electromagnetic fields.
引用
收藏
页码:8576 / 8590
页数:15
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