Synthesis, structural and vibrational properties of microcrystalline β-RbSm(MoO4)2

被引：66
|
作者：
Atuchin, V. V. [1 ]
Chimitova, O. D. [2 ]
Adichtchev, S. V. [3 ]
Bazarov, J. G. [2 ]
Gavrilova, T. A. [4 ]
Molokeev, M. S. [5 ]
Surovtsev, N. V. [3 ]
Bazarova, Zh. G. [2 ]
机构：
[1] SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia
[2] SB RAS, Baikal Inst Nat Management, Lab Oxide Syst, Ulan Ude 670047, Russia
[3] SB RAS, Inst Automat & Electrometry, Lab Condensed Matter Spect, Novosibirsk 630090, Russia
[4] SB RAS, Inst Semicond Phys, Lab Nanodiagnost & Nanolithog, Novosibirsk 630090, Russia
[5] SB RAS, Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia
来源：
MATERIALS LETTERS | 2013年 / 106卷
关键词：
beta-RbSm(MoO4)(2); Synthesis; Crystal structure; Raman spectroscopy; UP-CONVERSION PHOTOLUMINESCENCE; MOLYBDATES; CRYSTAL; GROWTH;
D O I：
10.1016/j.matlet.2013.04.039
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Low-temperature rubidium samarium dimolybdate, beta-RbSm(MoO4)(2), microplates have been prepared by solid state synthesis at 723 K by 70 h and 893 K by 150 h. The crystal structure of beta-RbSm(MoO4)(2) has been first refined by the Rietveld method in the space group Pbcn with unit cell parameters a = 5.1431(2) angstrom, b=18.8195(7) angstrom, and c=8.1641(3) angstrom (R-B=4.82%). The crystal structure of beta-RbSm(MoO4)(2) consists of the layers of MoO4 tetrahedrons corner-sharing with SmO8 square antiprisms. About 20 narrow Raman lines have been observed in Raman spectra recorded for the beta-RbSm(MoO4)(2) powder sample. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：26 / 29
页数：4
相关论文
共 50 条
  • [1] Synthesis, structural and vibrational properties of microcrystalline RbNd(MoO4)2
    Atuchin, V. V.
    Chimitova, O. D.
    Gavrilova, T. A.
    Molokeev, M. S.
    Kim, Sung-Jin
    Surovtsev, N. V.
    Bazarov, B. G.
    JOURNAL OF CRYSTAL GROWTH, 2011, 318 (01) : 683 - 686
  • [2] Structural and vibrational properties of microcrystalline TIM(MoO4)2 (M = Nd, Pr) molybdates
    Atuchin, V. V.
    Grossman, V. G.
    Adichtchev, S. V.
    Surovtsev, N. V.
    Gavrilova, T. A.
    Bazarov, B. G.
    OPTICAL MATERIALS, 2012, 34 (05) : 812 - 816
  • [3] High pressure effects on the structural and vibrational properties of antiferromagnetic KFe(MoO4)2
    Maczka, M
    Pietraszko, A
    Saraiva, GD
    Souza, AG
    Paraguassu, W
    Lemos, V
    Perottoni, CA
    Gallas, MR
    Freire, PTC
    Tomaszewski, PE
    Melo, FEA
    Mendes, J
    Hanuza, J
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2005, 17 (39) : 6285 - 6300
  • [4] Electronic structure of β-RbSm(MoO4)2 and chemical bonding in molybdates
    Atuchin, V. V.
    Aleksandrovsky, A. S.
    Chimitova, O. D.
    Diao, Cheng-Peng
    Gavrilova, T. A.
    Kesler, V. G.
    Molokeev, M. S.
    Krylov, A. S.
    Bazarov, B. G.
    Bazarova, J. G.
    Lin, Zheshuai
    DALTON TRANSACTIONS, 2015, 44 (04) : 1805 - 1815
  • [5] Exploration of structural, vibrational and spectroscopic properties of self-activated orthorhombic double molybdate RbEu(MoO4)2 with isolated MoO4 units
    Atuchin, Victor V.
    Aleksandrovsky, Aleksandr S.
    Bazarov, Bair G.
    Bazarova, Jibzema G.
    Chimitova, Olga D.
    Denisenko, Yuriy G.
    Gavrilova, Tatyana A.
    Krylov, Alexander S.
    Maximovskiy, Eugene A.
    Molokeev, Maxim S.
    Oreshonkov, Aleksandr S.
    Pugachev, Alexey M.
    Surovtsev, Nikolay V.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 785 : 692 - 697
  • [6] Structure and vibrational properties of tetragonal scheelite NaBi(MoO4)(2)
    Hanuza, J
    Haznar, A
    Maczka, M
    Pietraszko, A
    Lemiec, A
    vanderMaas, JH
    Lutz, ETG
    JOURNAL OF RAMAN SPECTROSCOPY, 1997, 28 (12) : 953 - 963
  • [7] Synthesis and Electronic Properties of β-RbNd(MoO4)2
    Atuchin, V. V.
    Bekenev, V. L.
    Chimitova, O. D.
    Molokeev, M. S.
    Bazarov, B. G.
    Bazarova, J. G.
    Khyzhun, O. Y.
    Lim, C. S.
    ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (05) : 1284 - 1286
  • [8] Synthesis and photoluminescence properties of HEu(MoO4)2 nanophosphor
    Watanabe, Mizuki
    Uematsu, Kazuyoshi
    Kim, Sun Woog
    Toda, Kenji
    Sato, Mineo
    JOURNAL OF CERAMIC PROCESSING RESEARCH, 2014, 15 (03): : 173 - 176
  • [9] Electronic structure and optical properties of β-RbSm(MoO4)2 from spin polarization calculations: DFT plus U
    Reshak, A. H.
    MATERIALS CHEMISTRY AND PHYSICS, 2017, 192 : 260 - 267
  • [10] Exploration of the Structural and Vibrational Properties of the Ternary Molybdate TI5BiHf(MoO4)6 with Isolated MoO4 Units and TI+ Conductivity
    Grossman, Victoria
    Adichtchev, Sergey, V
    Atuchin, Victor V.
    Bazarov, Bair G.
    Bazarova, Jibzema G.
    Kuratieva, Natalia
    Oreshonkov, Aleksandr S.
    Pervukhina, Natalia, V
    Surovtsev, Nikolay, V
    INORGANIC CHEMISTRY, 2020, 59 (17) : 12681 - 12689
12345