Photocatalytic Isomerization of 1-Butene over Palladium-Loaded Titanium(IV) Oxide Particles: Lewis Acid-like Features of the Photocatalyst

被引：16

作者：

Hashimoto, Keiji ^{[1
]}

Masuda, Yusuke ^{[1
]}

Kominami, Hiroshi ^{[1
]}

机构：

[1] Kinki Univ, Fac Sci & Engn, Dept Appl Chem, Higashiosaka, Osaka 5778502, Japan

来源：

ACS CATALYSIS | 2013年 / 3卷 / 06期

关键词：

photocatalyst; isomerization; 1-butene; TiO2; palladium; BUTENE ISOMERIZATION; NANOPARTICLES; REDUCTION; TIO2; SURFACE; HYDROGENATION; NITROBENZENE; CHEMISTRY; EXCHANGE; PROPENE;

D O I：

10.1021/cs4001514

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

1-Butene was isomerized to 2-butenes with a cis:trans ratio of similar to 2:1 over Pd/TiO2 under irradiation of UV light at room temperature, suggesting that a Pd/TiO2 photocatalyst can function as an effective substitute for a Lewis acid catalyst and that the reaction rate can be controlled by photon flux as in the case of changing temperature in a thermocatalytic system.

引用

页码：1349 / 1355

页数：7

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