Photocatalytic Isomerization of 1-Butene over Palladium-Loaded Titanium(IV) Oxide Particles: Lewis Acid-like Features of the Photocatalyst

被引：16
作者：
Hashimoto, Keiji [1 ]
Masuda, Yusuke [1 ]
Kominami, Hiroshi [1 ]
机构：
[1] Kinki Univ, Fac Sci & Engn, Dept Appl Chem, Higashiosaka, Osaka 5778502, Japan
来源：
ACS CATALYSIS | 2013年 / 3卷 / 06期
关键词：
photocatalyst; isomerization; 1-butene; TiO2; palladium; BUTENE ISOMERIZATION; NANOPARTICLES; REDUCTION; TIO2; SURFACE; HYDROGENATION; NITROBENZENE; CHEMISTRY; EXCHANGE; PROPENE;
D O I：
10.1021/cs4001514
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
1-Butene was isomerized to 2-butenes with a cis:trans ratio of similar to 2:1 over Pd/TiO2 under irradiation of UV light at room temperature, suggesting that a Pd/TiO2 photocatalyst can function as an effective substitute for a Lewis acid catalyst and that the reaction rate can be controlled by photon flux as in the case of changing temperature in a thermocatalytic system.
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页码：1349 / 1355
页数：7
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