The use of palladium nanoparticles supported on graphene oxide in the Mizoroki-Heck reaction

被引:24
作者
Ioni, Yu. V. [1 ]
Lyubimov, S. E. [2 ]
Davankov, V. A. [2 ]
Gubin, S. P. [1 ]
机构
[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
关键词
COUPLING REACTION; SUZUKI; DERIVATIVES; COMPLEXES; CATALYSTS;
D O I
10.1134/S0036023613040062
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
We have developed a convenient single-step method for producing palladium nanoparticles on the surface of graphene oxide by reducing palladium chloride with NaBH4. According to transmission electron microscopy data, palladium nanoparticles have a spheroidal shape; their sizes are 6-8 nm. The tests of immobilized palladium nanoparticles have shown that they exhibit high activity in the Mizoroki-Heck cross-coupling reaction.
引用
收藏
页码:392 / 394
页数:3
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