A brief introduction to transition metals in unusual oxidation states

被引:26
作者
Chan, Wesley Ting Kwok [1 ]
Wong, Wing-Tak [1 ]
机构
[1] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China
关键词
Transition metals; Unusual oxidation states; COPPER(III) PERIODATE COMPLEX; ASYMMETRIC COBALT ATOMS; NORMAL-BUTYL PHOSPHATE; HIGH OXYGEN PRESSURES; STRUCTURAL-CHARACTERIZATION; ORGANOMETALLIC CHEMISTRY; COORDINATION CHEMISTRY; CRYSTAL-STRUCTURES; CHEMICAL-BOND; TRIS(PHOSPHINO)SILYL LIGANDS;
D O I
10.1016/j.poly.2012.09.004
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
As we celebrate the 100th year since Alfred Werner's Nobel Prize in Chemistry award for his pioneering work on coordination chemistry, we look back in this review at some of the more prominent examples of transition metals in unusual oxidation states. This area of coordination chemistry has been studied by chemists all over the world for the best part of this past century, with applications being found in a vast array of environments. Hopefully, this simple review will allow us a glimpse of the great potential and possibility in the chemistry of transition metals in unusual oxidation states. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:43 / 61
页数:19
相关论文
共 221 条
[21]   Niobium(I) and tantalum(I) tetracarbonyl derivatives containing nitrogen ligands [J].
Bernieri, P ;
Calderazzo, F ;
Englert, U ;
Pampaloni, G .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 562 (01) :61-69
[22]   Isolation of a uranyl[UO2]+ species:: Crystallographic comparison of the dioxouranium(V) and (VI) compounds [UO2(OPPh3)4] (OTf)n (n=1, 2) [J].
Berthet, JC ;
Nierlich, M ;
Ephritikhine, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (17) :1952-1954
[23]   TRI-NORMAL-BUTYL PHOSPHATE AS AN EXTRACTING SOLVENT FOR INORGANIC NITRATES .3. THE PLUTONIUM NITRATES [J].
BEST, GF ;
MCKAY, HAC ;
WOODGATE, PR .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1957, 4 (5-6) :315-320
[24]  
Bethe H, 1929, ANN PHYS-BERLIN, V3, P133
[25]   Dinitrogen chemistry from trigonally coordinated iron and cobalt platforms [J].
Betley, TA ;
Peters, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (36) :10782-10783
[26]  
Bicher M., 1999, ROM BIOTECHNOL LETT, V4, P151
[27]  
Bicher M., 1999, ROM BIOTECHNOL LETT, V4, P129
[28]   The volatile metal carbonyls [J].
Blanchard, AA .
CHEMICAL REVIEWS, 1937, 21 (01) :3-38
[29]  
Bond GC, 2000, PLATIN MET REV, V44, P146
[30]   KINETICS AND MECHANISM OF SILVER(III) REDUCTION BY AZIDE ION IN AQUEOUS ALKALINE MEDIA [J].
BORISH, ET ;
KIRSCHENBAUM, LJ .
INORGANIC CHEMISTRY, 1984, 23 (15) :2355-2359