Character of the direct M-M bond in M(2)(CO)(8)(mu-PR(2))(2) complexes (M=V, Cr, Mn)

被引：4
|
作者：
Reinhold, J
Muller, B
Eichler, U
机构：
[1] Inst. F. Phys. und Theor. Chemie, Universität Leipzig
来源：
ORGANOMETALLICS | 1997年 / 16卷 / 07期
关键词：
METAL-METAL BOND; DIMERS; BINUCLEAR;
D O I：
10.1021/om960566p
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first ab-initio calculations of phosphido-bridged binuclear organometallic compounds are reported. By analysis of the influence of electron correlation on the complex molecular structure, conclusions can be drawn about the nature of the direct bonding interaction between the two metal centers. The formal M-M bond order overestimates the direct M-M bonding interaction in the V case but underestimates it in the Cr and Mn cases.
引用
收藏
页码：1497 / 1500
页数：4
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