Mathematical model of magnetite synthesis by oxidation of sulfuric pickling liquors from steelmaking

被引：7

作者：

Dufour, J ^{[1
]}

López, L ^{[1
]}

Negro, C ^{[1
]}

Latorre, R ^{[1
]}

Formoso, A ^{[1
]}

López-Mateos, F ^{[1
]}

机构：

[1] Univ Complutense Madrid, Fac Chem Sci, Dept Chem Engn, E-28040 Madrid, Spain

来源：

CHEMICAL ENGINEERING COMMUNICATIONS | 2002年 / 189卷 / 03期

关键词：

model; magnetite; oxidation; precipitation; pickling liquor;

D O I：

10.1080/00986440212080

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The aim of this paper is to propose a model obtained through experimental design which represents the synthesis of magnetite by oxidation-precipitation of sulfuric liquors from steel pickling. The studied variables are pH (5.5-6.5), stirring speed (250-1,000 rev.min(-1)) and flow of air used as oxidizer (5-101.min(-1)). The model is valid within the experimental ranges and for a temperature of 70degreesC. The proposed model is validated through statistical methods. The influence of each variable is studied related to the reaction mechanism and the optimal value of each one is determined.

引用

页码：285 / 297

页数：13

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