Electro-Optical and Electrochemical Properties of Poly(2-ethynylpyridine)

被引：5

作者：

Gal, Yeong-Soon ^{[1
]}

Suh, Han-Na ^{[1
]}

Lee, Won-Chul ^{[1
]}

Jin, Sung-Ho ^{[2
]}

Park, Jong-Wook ^{[3
,4
]}

Lyoo, Won Seok ^{[5
]}

Shim, Sang-Yeon ^{[6
]}

Lim, Kwon Taek ^{[7
]}

机构：

[1] Kyungil Univ, Coll Engn, Polymer Chem Lab, Kyungsan, South Korea

[2] Pusan Natl Univ, Dept Chem Educ, Pusan 609735, South Korea

[3] Catholic Univ, Dept Chem, Puchon, South Korea

[4] Catholic Univ, Ctr Nanotech Res, Puchon, South Korea

[5] Yeungnam Univ, Sch Text, Gyongsan, South Korea

[6] Kangneung Natl Univ, Dept Environm & Appl Chem Engn, Kangnung, South Korea

[7] Pukyong Natl Univ, Div Image & Informat Engn, Pusan, South Korea

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2008年 / 491卷

关键词：

2-ethynylpyridine; catalyst; conjugated polymer; cyclovoltamogram; electro-optical; polyacetylene;

D O I：

10.1080/15421400802331075

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electro-optical and electrochemical properties of poly(2-ethynylpyridine) was studied and discussed. Poly(2-ethynylpyridine) was prepared by the polymerization of 2-ethynylpyridine by using the catalyst of WCl6-EtAlCl2. The photoluminescence (PL) spectra of the polymer showed that the photoluminescence peak is located at 581nm, corresponding to a photon energy of 2.14eV. The cyclic voltamograms of polymer exhibited reversible electrochemical behaviors between the doped and undoped peaks. The kinetics of the redox process of polymer was controlled by the diffusion process from the experiment plotting the oxidation current density of polymer versus the scan rate.

引用

页码：348 / 355

页数：8

共 50 条

[41] Linear electro-optical properties of zincite
Shaldin, YV
OPTICS AND SPECTROSCOPY, 2004, 97 (03) : 381 - 387
[42] ELECTRO-OPTICAL PROPERTIES OF RODLIKE MICELLES
HOFFMANN, H
SCHORR, W
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1985, 89 (05): : 538 - 545
[43] ELECTRO-OPTICAL PROPERTIES OF DNA SOLUTIONS
DVORKIN, GA
BIOPHYSICS-USSR, 1961, 6 (04): : 16 - &
[44] Electro-optical properties of poly(N-vinyl carbazole) nanoclay composites
Ozerol, Esma Ahlatcioglu
POLYMER BULLETIN, 2019, 76 (10) : 5301 - 5311
[45] Poly(triphenylamine)s Derived from Oxidative Coupling Reaction: Substituent Effects on the Polymerization, Electrochemical, and Electro-Optical Properties
Lin, Hung-Yi
Liou, Guey-Sheng
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (01) : 285 - 294
[46] On the electro-optical properties of mixed liquids
Chaudier, J
ANNALES DE CHIMIE ET DE PHYSIQUE, 1908, 15 : 67 - 140
[47] Electro-optical properties of poly(N-vinyl carbazole) nanoclay composites
Esma Ahlatcıoğlu Özerol
Polymer Bulletin, 2019, 76 : 5301 - 5311
[48] THE SYNTHESIS, CHARACTERIZATION AND ELECTRO-OPTICAL PROPERTIES OF POLY(PENTENYLENE-B-ACETYLENE)
FARREN, TR
AMASS, AJ
BEEVERS, MS
STOWELL, JA
POLYMER, 1989, 30 (06) : 1008 - 1011
[49] Synthesis and properties of an ionic polyacetylene by the activated polymerization of 2-ethynylpyridine with the ring-opening of propiolactone
Gal, Yeong-Soon
Jin, Sung-Ho
Park, Young-Il
Park, Jong-Wook
Lyoo, Won Seok
Lim, Kwon-Taek
SYNTHETIC METALS, 2011, 161 (5-6) : 445 - 449
[50] Synthesis and electro-optical properties of poly(2-ethynylpyridinium tosylate) having propagyl side chain
Gal, YS
Lee, WC
Lee, SJ
Park, JW
Ko, JM
Chun, JH
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 1999, A36 (10): : 1503 - 1519

← 1 2 3 4 5 →