Gold-Palladium Core-Shell Nanocrystals with Size and Shape Control Optimized for Catalytic Performance

被引：96
作者：
Henning, Anna M. [1 ,2 ]
Watt, John [1 ,2 ]
Miedziak, Peter J. [3 ,4 ]
Cheong, Soshan [5 ,6 ]
Santonastaso, Marco [3 ,4 ]
Song, Minghui [7 ]
Takeda, Yoshihiko [8 ]
Kirkland, Angus I. [9 ]
Taylor, Stuart H. [3 ,4 ]
Tilley, Richard D. [1 ,2 ]
机构：
[1] Victoria Univ Wellington, Sch Chem & Phys Sci, Wellington 6012, New Zealand
[2] Victoria Univ Wellington, MacDiarmid Inst Adv Mat & Nanotechnol, Wellington 6012, New Zealand
[3] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales
[4] Cardiff Univ, Cardiff Catalysis Inst, Cardiff CF10 3AT, S Glam, Wales
[5] Ind Res Ltd, Lower Hutt 5040, New Zealand
[6] MacDiarmid Inst Adv Mat & Nanotechnol, Lower Hutt 5040, New Zealand
[7] Natl Inst Mat Sci, Adv Key Technol Div, Surface Phys & Struct Unit, Tsukuba, Ibaraki 3050047, Japan
[8] Natl Inst Mat Sci, Adv Key Technol Div, Quantum Beam Unit, Tsukuba, Ibaraki 3050003, Japan
[9] Univ Oxford, Dept Mat, Oxford OX1 3PH, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 05期
基金：
英国工程与自然科学研究理事会;
关键词：
bimetallic nanoparticles; core-shell structures; gold; heterogeneous catalysis; palladium; METAL NANOCRYSTALS; HYDROGEN-PEROXIDE; AU; GROWTH; NANOPARTICLES; FABRICATION; MORPHOLOGY; OXIDATION; KINETICS; H-2;
D O I：
10.1002/anie.201207824
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Right to the core: The design of nanocatalysts with maximized catalytic performance relies on control of the size, shape, and composition. The shell thickness of nanocrystals with core-shell structures can be controlled, thus enabling control over the nanocrystal electronic structure and catalytic properties. Monodisperse faceted icosahedral Au-Pd core-shell nanocrystals (see picture) were synthesized, and optimized for the oxidation of benzyl alcohol to benzaldehyde. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1477 / 1480
页数：4
相关论文
共 50 条
  • [21] Highly strained gold (Au)-palladium (Pd) core-shell nanobipyramids with extraordinary high activity and durability towards ethanol electrooxidation
    Singha, Tukai
    Mishra, Smruti Medha
    Chini, Tapas Kumar
    Satpati, Biswarup
    APPLIED SURFACE SCIENCE, 2022, 604
  • [22] Controlled synthesis of non-epitaxially grown Pd@Ag core-shell nanocrystals of interesting optical performance
    Gong, Jianxiao
    Zhou, Fei
    Li, Zhiyuan
    Tang, Zhiyong
    CHEMICAL COMMUNICATIONS, 2013, 49 (39) : 4379 - 4381
  • [23] Exchange-Coupled Bimagnetic Wustite/Metal Ferrite Core/Shell Nanocrystals: Size, Shape, and Compositional Control
    Bodnarchuk, Maryna I.
    Kovalenko, Maksym V.
    Groiss, Heiko
    Resel, Roland
    Reissner, Michael
    Hesser, Guenter
    Lechner, Rainer T.
    Steiner, Walter
    Schaeffler, Friedrich
    Heiss, Wolfgang
    SMALL, 2009, 5 (20) : 2247 - 2252
  • [24] Facile synthesis of Au-Pd core-shell nanocrystals with systematic shape evolution and tunable size for plasmonic property examination
    Chiu, Chun-Ya
    Yang, Min-Yi
    Lin, Fan-Cheng
    Huang, Jer-Shing
    Huang, Michael H.
    NANOSCALE, 2014, 6 (13) : 7656 - 7665
  • [25] Photochemical Synthesis and Characterization of Gold @ Palladium Core-Shell Composite Nanoparticles
    Dong Ying-Nan
    Dong Shou-An
    Tang Chun
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2009, 30 (07): : 1397 - 1401
  • [26] Core-Size-Dependent Catalytic Properties of Bimetallic Au/Ag Core-Shell Nanoparticles
    Haldar, Krishna Kanta
    Kundu, Simanta
    Patra, Amitava
    ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (24) : 21946 - 21953
  • [27] Plasma-activated core-shell gold nanoparticle films with enhanced catalytic properties
    Llorca, Jordi
    Casanovas, Albert
    Dominguez, Montserrat
    Casanova, Ignasi
    Angurell, Inmaculada
    Seco, Miquel
    Rossell, Oriol
    JOURNAL OF NANOPARTICLE RESEARCH, 2008, 10 (03) : 537 - 542
  • [28] Synthesis and catalytic activity of monodisperse gold-mesoporous silica core-shell nanocatalysts
    Sekhar, A. C. Sunil
    Meera, C. J.
    Ziyad, K. V.
    Gopinath, Chinnakonda S.
    Vinod, C. P.
    CATALYSIS SCIENCE & TECHNOLOGY, 2013, 3 (05) : 1190 - 1193
  • [29] Plasma-activated core-shell gold nanoparticle films with enhanced catalytic properties
    Jordi Llorca
    Albert Casanovas
    Montserrat Domínguez
    Ignasi Casanova
    Inmaculada Angurell
    Miquel Seco
    Oriol Rossell
    Journal of Nanoparticle Research, 2008, 10 : 537 - 542
  • [30] Crystallinity Variation in Seeded Growth of Gold@Silver Core-Shell Nanocrystals: Truncated Right Bipyramids and Their Hollow Derivatives
    Zhang, Gongguo
    Fu, Xiaowei
    Luan, Xiaoqian
    Zhai, Xiurong
    Qu, Fengli
    Zheng, Yiqun
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 2020 (31) : 2950 - 2954
12345