A metal-organic framework made of an asymmetric 1,2,4-triazole and tetrazole ligand

被引：18

作者：

Boland, Yves ^{[1
]}

Tinant, Bernard ^{[1
]}

Safin, Damir A. ^{[1
]}

Marchand-Brynaert, Jacqueline ^{[1
]}

Clerac, Rodolphe ^{[2
,3
]}

Garcia, Yann ^{[1
]}

机构：

[1] Catholic Univ Louvain, MOST Chem, Inst Condensed Matter & Nanosci, B-1348 Louvain, Belgium

[2] CNRS, CRPP, UPR 8641, F-33600 Pessac, France

[3] Univ Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 23期

关键词：

COORDINATION POLYMERS; CRYSTAL-STRUCTURE; SPIN TRANSITION; MAGNETIC-PROPERTIES; COPPER(II); 1,2-BIS(1,2,4-TRIAZOL-4-YL)ETHANE; POLYNUCLEAR; FLUORESCENT; ASSEMBLIES; CROSSOVER;

D O I：

10.1039/c2ce26257f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the asymmetric ligand, 1-[3'-(1,2,4-triazol-4-yl) propyl] tetrazole (L) with Cu(BF4)(2) in water leads to the Cu-II metal-organic framework [CuL(OH)]BF4 (I). According to X-ray analysis, L connects four Cu-II ions, where the 1,2,4-triazole and tetrazole units exhibit a bridging bis-monodentate mu(2)-N1, N2 and a unique mu(2)-N2, N3 coordination modes, respectively.

引用

页码：8153 / 8155

页数：3

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