Synthesis and characterization of perfluorocyclobutyl aryl ether-based amphiphilic diblock copolymer

Perfluorocyclobutyl aryl ether-based amphiphilic diblock copolymer containing hydrophilic poly (ethylene glycol) segment was synthesized by atom transfer radical polymerization (ATRP). Perfluorocyclobutyl-containing methacrylate-based monomer, 4-(4'-p-tolyfoxyperfluorocyclobutoxy)benzyl methacrylate, was prepared firstly, which can be polymerized by ATRP in a controlled way to obtain well-defined homopolymers with narrow molecular weight distributions (M-w/M-n <= 1.30). The molecular weights increased linearly with the conversions of monomer and the apparent polymerization rate exhibited first-order relation with respect to the concentration of monomer. ATRP of 4-(4'-p-tolyloxyperfluorocyclobutoxy)benzyl methacrylate was initiated by PEG-based macroinitiators with different molecular weights to obtain amphiphilic diblock copolymers with narrow molecular weight distributions (M-w/M-n < 1.35) and the number of perfluorocyclobutyl linkage can be tuned by the feed ratio and the conversion of the fluorine-containing methacrylate monomer. The critical micelle concentrations of these amphiphilic diblock copolymers in water and brine were determined by fluorescence probe technique. The morphologies of the micelles were found to be spheres by TEM. (C) 2008 Elsevier Ltd. All rights reserved.