A catalytic enantioselective electron transfer reaction:: Titanocene-catalyzed enantioselective formation of radicals from meso-epoxides

被引：0

作者：

Gansäuer, A

Lauterbach, T

Bluhm, H

Noltemeyer, M

机构：

[1] Univ Freiburg, Inst Organ Chem & Biochem, D-79104 Freiburg, Germany

[2] Univ Gottingen, Inst Anorgan Chem, D-3400 Gottingen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 19期

关键词：

enantioselectivity; epoxides; homogeneous catalysis; radical reactions; titanium;

D O I：

10.1002/(SICI)1521-3773(19991004)38:19<2909::AID-ANIE2909>3.0.CO;2-Y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rationally designed titanium(III) catalyst allows the opening of epoxides with. high enantioselectivity. This reaction [Eq. (1)] constitutes the first example of an enantioselective transition metal catalyzed radical reaction that proceeds by electron transfer.

引用

页码：2909 / 2910

页数：2