Contraction of the six-membered alicyclic ring of perfluorinated ethyl- and diethyl-tetralins to five- and four-membered ones under the action of antimony pentafluoride

被引：8

作者：

Karpov, VM

Mezhenkova, TV

Platonov, VE

机构：

[1] Institute of Organic Chemistry

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 77卷 / 01期

关键词：

alicycle contraction; perfluorinated ethyltetralins; perfluorinated diethyltetralins; antimony pentafluoride; NMR spectroscopy;

D O I：

10.1016/0022-1139(95)03383-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Interaction of perfluoro-1-ethyltetralin (2) with SbF5 leads to the formation of perfluorinated 5-ethyltetralin (5), 3-methyl-4-ethylindan (6) and 1,3,4-trimethylindan (4). Perfluoro-1,4-diethyltetralin (3) under the action of SbF5 gives perfluorinated 5,8-diethyltetralin (8), 1-methyl-4,7-diethylindan (9) and 1,1-dimethyl-3,6-diethylbenzocyclobutene (10).

引用

页码：101 / 103

页数：3

共 6 条

[1] RING CONTRACTION IN THE REACTION OF POLYFLUORINATED TETRALINES WITH ANTIMONY PENTAFLUORIDE - FORMATION OF POLYFLUORINATED INDANES FROM TETRALINES [J].