Titanium-containing compounds as efficient triboadditives to oils

被引:6
作者
Zaimovskaya, T. A. [1 ]
Oganesova, E. Yu [1 ]
Kuzmina, G. N. [1 ]
Ezhov, A. A. [1 ]
Ivanov, V. K. [2 ]
Parenago, O. P. [1 ]
机构
[1] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow 119991, Russia
[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia
关键词
titanium carboxylates; titanium dioxide nanoparticles; modifiers; antiwear properties; coefficient of friction; surface profile; titanium atoms; FRICTION; ANTIWEAR;
D O I
10.3103/S1068366613060135
中图分类号
TH [机械、仪表工业];
学科分类号
0802 ;
摘要
Titanium-containing compounds soluble in mineral oils, such as titanium oleate and titanium 2-ethylhexanoate, as well as titanium dioxide nanoparticles modified by tetra(2-ethylhexyl)-thiuramdisulfide (TDS) and di(2-ethylhexyl)thiophonedisulfide (TFDS), were synthesized. Small-angle X-ray scattering was used to identify the structure of titanium carboxylates and determine the size of TiO2 nanoparticles. The antifriction and antiwear characteristics of these compounds were studied in various-type tribometers equipped with a four-ball friction unit. A comparative study of titanium-containing compounds with the highest tribological characteristics that contained nanoparticles modified by TDS and 2-ethylhexane acid at increasing velocity of sliding was carried out. The effect of titanium-containing compounds on the relief of worn surfaces was investigated.
引用
收藏
页码:487 / 493
页数:7
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