Comprehensive characterization and environmental risk assessment of end-of-life automotive catalytic converters to arrange a sustainable roadmap for future recycling practices

Environmentally appropriate economic recycling of spent automotive catalytic converters (SACCs) is difficult due to their complexity. The prominent reason is the lack of knowledge and comprehensive characterization of SACCs. This study focused on the characterization of SACCs in terms of their structural, morphological, physiochemical, surface, and thermal properties. The accurate determination of metals content, including 4975 mg/kg platinum group metals, 42,119 mg/kg rare earth elements, and other base metals, showed a great potential wealth in SACCs. Besides, the sequential extraction method was applied for metals fractionation, which represents a unique harsh recycling approach needed due to the stable structure of SACCs, metals embedded in silicate phases, and the presence of barely soluble metal phosphates. This waste was also examined for environmental criteria and leaching tests, including Toxicity Characteristic Leaching Procedure, Waste Extraction Test, and Synthetic Precipitation Leaching Procedure. The findings declare that Waste Extraction Test was the most aggressive procedure to assess mobility. The contamination indexes, such as risk assessment code, contamination factor, and global contamination factor, were also investigated, which show SACCs must be regarded as hazardous waste. As an example, the global contamination factor of 11.87 depicts SACCs have a moderate contamination degree.