Direct Construction of Quaternary Carbons from Tertiary Alcohols via Photoredox-Catalyzed Fragmentation of tert-Alkyl N-Phthalimidoyl Oxalates

被引：259

作者：

Lackner, Gregory L. ^{[1
]}

Quasdorf, Kyle W. ^{[1
]}

Overman, Larry E. ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 41期

基金：

美国国家科学基金会;

关键词：

RADICAL REACTIONS; ADDITIONS; LIGHT; DERIVATIVES; XANTHATES; INVENTION; ALKENES; BONDS;

D O I：

10.1021/ja408971t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A convenient method for the direct construction of quaternary carbons from tertiary alcohols by visible-light photoredox coupling of tert-alkyl N-phthalimidoyl oxalate intermediates with electron-deficient alkenes is reported.

引用

页码：15342 / 15345

页数：4

共 2 条

[1] Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N-Phthalimidoyl Oxalates By Visible-Light Photocatalysis
Lackner, Gregory L.
Quasdorf, Kyle W.
Pratsch, Gerald
Overman, Larry E.
JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (12): : 6012 - 6024
[2] Direct construction of aryl amide N-glycosides from glycosyl oxamic acids via photoredox palladium-catalyzed aminocarbonylations
Xie, Xinyue
Zhao, Shiyin
Han, Yang
Chen, Anrong
Yang, Bo
Zhu, Bo
Li, Yingzi
Zhou, Jun
Zhu, Feng
CHEM CATALYSIS, 2024, 4 (10):

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