Direct Construction of Quaternary Carbons from Tertiary Alcohols via Photoredox-Catalyzed Fragmentation of tert-Alkyl N-Phthalimidoyl Oxalates

被引：270

作者：

Lackner, Gregory L. ^{[1
]}

Quasdorf, Kyle W. ^{[1
]}

Overman, Larry E. ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 41期

基金：

美国国家科学基金会;

关键词：

RADICAL REACTIONS; ADDITIONS; LIGHT; DERIVATIVES; XANTHATES; INVENTION; ALKENES; BONDS;

D O I：

10.1021/ja408971t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A convenient method for the direct construction of quaternary carbons from tertiary alcohols by visible-light photoredox coupling of tert-alkyl N-phthalimidoyl oxalate intermediates with electron-deficient alkenes is reported.

引用

页码：15342 / 15345

页数：4

共 27 条

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