Synthesis of Mg(OH)2, MgO, and Mg nanoparticles using laser ablation of magnesium in water and solvents

被引:106
作者
Phuoc, Tran X. [1 ]
Howard, Bret. H. [1 ]
Martello, Donald V. [1 ]
Soong, Yee [1 ]
Chyu, Minking K. [2 ]
机构
[1] Natl Energy Technol Lab, Pittsburgh, PA 15236 USA
[2] Univ Pittsburgh, Dept Mech Engn & Mat Sci, Pittsburgh, PA 15261 USA
关键词
laser ablation in liquid; magnesium; magnesium oxides;
D O I
10.1016/j.optlaseng.2008.05.018
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Laser ablation of magnesium in deionized water (DW), solutions of DW and sodium dodecyl sulfate (SDS) with different concentrations, acetone and 2-propanol has been conducted. The results showed that ablation in acetone and 2-propanol yielded MgO and Mg nanocrystallites as isolated particles and agglomerated chains probably intermixed with organic residues resulting from the alteration/decomposition of the solvents under the high-energy conditions. Brucite-like Mg(OH)2 particles were mainly produced by laser ablation of Mg in either DW or DW-SDS solutions. Ablation in DW yielded particles of fiber-like shapes having a diameter of about 5-10nm and length-as long as 150 nm. Materials produced in DW-SDS solutions were composed of various size and shape particles. Some had rough surfaces with irregular shapes. Small particles were about 20-30 nm and larger particles were about 120 nm. Particles with rod-like, triangular, and plate-like shapes were also observed. Published by Elsevier Ltd.
引用
收藏
页码:829 / 834
页数:6
相关论文
共 23 条
[1]   Formation of nanoparticles during double-pulse laser ablation of metals in liquids [J].
Burakov, VS ;
Tarasenko, NV ;
Butsen, AV ;
Rozantsev, VA ;
Nedel'ko, MI .
EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 2005, 30 (02) :107-112
[2]   First hyperpolarizabilities of unprotected and polymer protected copper nanoparticles prepared by laser ablation [J].
Chandra, M ;
Indi, SS ;
Das, PK .
CHEMICAL PHYSICS LETTERS, 2006, 422 (1-3) :262-266
[3]   A convenient way to prepare magnetic colloids by direct Nd:YAG laser ablation [J].
Chen, GX ;
Hong, MH ;
Lan, B ;
Wang, ZB ;
Lu, YF ;
Chong, TC .
APPLIED SURFACE SCIENCE, 2004, 228 (1-4) :169-175
[4]   Nanoparticles produced by laser ablation of solids in liquid environment [J].
Dolgaev, SI ;
Simakin, AV ;
Voronov, VV ;
Shafeev, GA ;
Bozon-Verduraz, F .
APPLIED SURFACE SCIENCE, 2002, 186 (1-4) :546-551
[5]   Intermediate phase upon alloying Au-Ag nanoparticles under laser exposure of the mixture of individual colloids [J].
Izgaliev, AT ;
Simakin, AV ;
Shafeev, GA ;
Bozon-Verduraz, F .
CHEMICAL PHYSICS LETTERS, 2004, 390 (4-6) :467-471
[6]   Laser induced synthesis of nanoparticles in liquids [J].
Kazakevich, P. V. ;
Simakin, A. V. ;
Voronov, V. V. ;
Shafeev, G. A. .
APPLIED SURFACE SCIENCE, 2006, 252 (13) :4373-4380
[7]   Pulsed-laser ablation of Mg in liquids: surfactant-directing nanoparticle assembly for magnesium hydroxide nanostructures [J].
Liang, CH ;
Sasaki, T ;
Shimizu, Y ;
Koshizaki, N .
CHEMICAL PHYSICS LETTERS, 2004, 389 (1-3) :58-63
[8]  
Nichols W. T., 2006, J APPL PHYS, V100
[9]  
Nichols W. T., 2006, J APPL PHYS, V100
[10]   Synthesis of Ag-deionized water nanofluids using multi-beam laser ablation in liquids [J].
Phuoc, Tran X. ;
Soong, Yee ;
Chyu, Minking K. .
OPTICS AND LASERS IN ENGINEERING, 2007, 45 (12) :1099-1106