Cucurbit[7]uril and o-carborane self-assemble to form a molecular ball bearing

被引：121

作者：

Blanch, RJ ^{[1
]}

Sleeman, AJ ^{[1
]}

White, TJ ^{[1
]}

Arnold, AP ^{[1
]}

Day, AI ^{[1
]}

机构：

[1] Univ Coll New S Wales, Sch Chem, ADFA, Canberra, ACT, Australia

来源：

NANO LETTERS | 2002年 / 2卷 / 02期

关键词：

D O I：

10.1021/nl015655s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-assembly of cucurbit[7]uril (W) with o-carborane (1) produces a molecular ball bearing nanostructure (2). While investigating the possible role of o-carborane as a template for the controlled synthesis of 07, new synthetic reaction conditions were discovered. Both the solvent and the reaction temperature had a marked effect on the relative percentages of cuourbit[n]uril (n = 5, 6, 7, 8) produced. The effect of the o-carborane in the reaction mixture is discussed.

引用

页码：147 / 149

页数：3

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