Photochemistry of CS2/Cl complexes -: combined pulse radiolysis-laser flash photolysis studies

被引：4

作者：

Sumiyoshi, T ^{[1
]}

Nakayama, M ^{[1
]}

Fujiyoshi, R ^{[1
]}

Sawamura, S ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Quantum Sci & Engn, Kita Ku, Sapporo, Hokkaido 0608628, Japan

来源：

RADIATION PHYSICS AND CHEMISTRY | 2006年 / 75卷 / 01期

关键词：

CS2/Cl complex; pulse radiolysis; laser flash photolysis; intermolecular hydrogen abstraction;

D O I：

10.1016/j.radphyschem.2005.06.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Complexes of chlorine atoms and carbon disulfide (CS2) were produced by pulse radiolysis of CS2 in halocarbons and photochemical reactions were studied by laser flash photolysis. Excitation of CS2/Cl complexes resulted in rapid and permanent photobleaching. The photobleachling of CS2/Cl complexes is due to intermolecular chlorine atom abstraction in CCl4 with a quantum yield of 0.04, while that ascribed to hydrogen atom abstraction in 1,2-dichloroethane has a quantum yield of 0.21. The effects of additives are discussed based on the bond dissociation energy. (C) 2005 Elsevier Ltd. All rights reserved.

引用

页码：20 / 25

页数：6

共 23 条

[21] Laser flash photolysis studies of tris(2,2′-bipyridine)nickel(II) ion in aqueous solution
Banu, I. Sadhiya
Prakash, H.
Natarajan, P.
INORGANICA CHIMICA ACTA, 2011, 372 (01) : 429 - 435
[22] Effect of temperature on the absorption spectra of the solvated electron in 1-propanol and 2-propanol: Pulse radiolysis and laser photolysis studies at temperatures up to supercritical condition
Han, Zhenhui
Katsumura, Yosuke
Lin, Mingzhang
He, Hui
Muroya, Yusa
Kudo, Hisaaki
RADIATION PHYSICS AND CHEMISTRY, 2008, 77 (04) : 409 - 415
[23] Steady-state and laser flash photolysis studies on the oxidative splitting of cyclobutane thymine dimer by triplet 9,10-anthraquinone-2-sulfonate
Sheng, ZY
Pan, Y
Yan, LQ
Hei, XM
Guo, ZY
Dai, JH
Song, QH
Yu, SQ
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 161 (2-3) : 99 - 104

← 1 2 3 →