Highly Selective Hydrogenolysis of Glycerol to 1,3-Propanediol over a Boehmite-Supported Platinum/Tungsten Catalyst

被引：166

作者：

Arundhathi, Racha ^{[1
]}

Mizugaki, Tomoo ^{[1
]}

Mitsudome, Takato ^{[1
]}

Jitsukawa, Koichiro ^{[1
]}

Kaneda, Kiyotomi ^{[1
,2
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Mat Engn Sci, Toyonaka, Osaka 5608531, Japan

[2] Osaka Univ, Res Ctr Solar Energy Chem, Toyonaka, Osaka 5608531, Japan

来源：

CHEMSUSCHEM | 2013年 / 6卷 / 08期

关键词：

1; 3-propanediol; glycerol; heterogeneous catalyst; hydrogenolysis; platinum nanoparticle; CONVERSION; 1,2-PROPANEDIOL; ADSORPTION; ALCOHOLS; ALUMINA; PD;

D O I：

10.1002/cssc.201300196

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Business is boehming: Boehmite-supported platinum nanoparticles and tungsten oxides exhibit high catalytic activity towards the selective hydrogenolysis of glycerol to 1,3-propanediol. The reaction furthermore proceeds efficiently in aqueous solution without the requirement for any additives. This solid catalyst also demonstrates excellent durability, maintaining high catalytic activity and selectivity during recycling experiments. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1345 / 1347

页数：3

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