Transition metal-directed self-assembly of calix[4]arene based dithiocarbamate ligands

被引：23
|
作者：
Webber, PRA
Drew, MGB
Hibbert, R
Beer, PD
机构：
[1] Univ Oxford, Dept Chem, Inorgan Chem Lab, Oxford OX1 3QR, England
[2] Univ Reading, Dept Chem, Reading RG6 2AD, Berks, England
来源：
DALTON TRANSACTIONS | 2004年 / 08期
关键词：
D O I：
10.1039/b400929k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The transition metal-directed self-assembly of dithiocarbamate ligand functionalised upper and lower rim calix[4]arenes affords novel dimeric bimetallic bis(calix[4]arene) species as determined by a combination of analytical methods including X-ray crystallography. An exception is a zinc(II) dithiocarbamate upper rim calix[4]arene assembly which is monomeric in nature. Electrochemical investigations reveal the bimetallic copper(II) bis(calix[4]arene) systems can electrochemically sense dihydrogen phosphate and carboxylate anions via significant cathodic perturbations of the respective copper(II)/(III) dithiocarbamate oxidation wave.
引用
收藏
页码：1127 / 1135
页数：9
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