Simulation of Syngas Production from Lignin Using Guaiacol as a Model Compound

被引：13

作者：

Eloisa Rodriguez-Olalde, Nancy ^{[1
]}

Alejandro Mendoza-Chavez, Erick ^{[1
]}

Jaime Castro-Montoya, Agustin ^{[1
]}

Saucedo-Luna, Jaime ^{[1
]}

Maya-Yescas, Rafael ^{[1
]}

Guadalupe Rutiaga-Quinones, Jose ^{[2
]}

Ponce Ortega, Jose Maria ^{[1
]}

机构：

[1] Univ Michoacana, Fac Ingn Quim, Morelia 58060, Michoacan, Mexico

[2] Univ Michoacana, Fac Ingn Tecnol Madera, Morelia 58060, Michoacan, Mexico

来源：

ENERGIES | 2015年 / 8卷 / 07期

关键词：

gasification of lignin; guaiacol as lignin model compound; syngas production; DIRECT THERMAL-DECOMPOSITION; THERMODYNAMIC ANALYSIS; HYDROGEN-PRODUCTION; GASIFICATION; PERFORMANCE; BIOMASS; GAS; ETHANOL; ENERGY; WATER;

D O I：

10.3390/en8076705

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Lignin is an abundant component in biomass that can be used a feedstock for producing several value-added products, including biofuels. However, lignin is a complex molecule (involving in its structure three types of phenylpropane units: coumaryl, coniferyl and sinapyl), which is difficult to implement in any process simulation task. The lignin from softwood is formed mainly by coniferyl units; therefore, in this work the use of the guaiacol molecule to model softwood lignin in the simulation of the syngas process (H-2 + CO) is proposed. A Gibbs reactor in ASPEN PLUS (R) was feed with ratios of water and guaiacol from 0.5 to 20. The pressure was varied from 0.05 to 1.01 MPa and the temperature in the range of 200-3200 degrees C. H-2, CO, CO2, CH4, O-2 and C as graphite were considered in the output stream. The pressure, temperature and ratio water/guaiacol conditions for syngas production for different H-2/CO ratio are discussed. The obtained results allow to determine the operating conditions to improve the syngas production and show that C as graphite and water decomposition can be avoided.

引用

页码：6705 / 6714

页数：10

共 50 条

[21] Syngas production from wood pellet using filtration combustion of lean natural gas-air mixtures [J].

Araus, Karina ;

Reyes, Felipe ;

Toledo, Mario .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (15) :7819-7825

[22] Enhancement of the quality of syngas from catalytic steam gasification of biomass by the addition of methane/model biogas [J].

Shen, Yalan ;

Liu, Yang ;

Yu, Haimiao .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (45) :20428-20437

[23] Syngas production from pyrolysis-catalytic steam reforming of waste biomass in a continuous screw kiln reactor [J].

Efika, Chidi E. ;

Wu, Chunfei ;

Williams, Paul T. .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2012, 95 :87-94

[24] Carbon dioxide-mediated catalytic pyrolysis of lignin in syngas production [J].

Kim, Minyoung ;

Choi, Dongho ;

Kim, Jee Young ;

Park, Seong-Jik ;

Kwon, Eilhann E. .

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2025, 296

[25] Green synthesis of Ni supported hematite catalysts for syngas production from catalytic cracking of toluene as a model compound of biomass tar [J].

Zou, Xuehua ;

Ma, Zhiyuan ;

Liu, Haibo ;

Chen, Dong ;

Wang, Can ;

Zhang, Ping ;

Chen, Tianhu .

FUEL, 2018, 217 :343-351

[26] Production of Hydrogen-Rich Syngas from Lignite using Different Pyrolysis Methods [J].

Wang, Qing-dong ;

Wang, Guang-hua ;

Li, Wen-bing ;

Chen, Biao .

ENERGY TECHNOLOGY, 2016, 4 (06) :751-757

[27] Thermodynamic analysis and process simulation of syngas production from methane using CoWO4 as oxygen carrier [J].

Lopez-Ortiz, A. ;

Gonzalez-Vargas, P. E. ;

Melendez-Zaragoza, M. J. ;

Collins-Martinez, V. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (51) :30223-30236

[28] PRODUCTION OF SYNGAS FROM BIOMASS [J].

MASCHIO, G ;

LUCCHESI, A ;

STOPPATO, G .

BIORESOURCE TECHNOLOGY, 1994, 48 (02) :119-126

[29] Liquid fuel production from syngas: Simulation and optimization using artificial neural network [J].

Al-Zuhairi, Firas K. ;

Shakor, Zaidoon M. ;

Azeez, Rana Abbas ;

Al-Shafei, Emad N. .

FUEL, 2024, 371

[30] Hydrodeoxygenation of guaiacol as a model compound of pyrolysis lignin-oil over NiCo bimetallic catalyst: Reactivity and kinetic study [J].

Tian, Zhipeng ;

Liang, Xuebin ;

Li, Rongxuan ;

Wang, Chao ;

Liu, Jianping ;

Lei, Libin ;

Shu, Riyang ;

Chen, Ying .

FUEL, 2022, 308

← 1 2 3 4 5 →