A green synthesis of 3,4-dihydropyrimidine-2(1H)-one/thione derivatives using nanosilica-supported tin(II) chloride as a heterogeneous nanocatalyst

被引：44

作者：

Ghomi, Javad Safaei ^{[1
]}

Teymuri, Raheleh ^{[1
]}

Ziarati, Abolfazl ^{[1
]}

机构：

[1] Univ Kashan, Fac Chem, Dept Organ Chem, Kashan 51167, Iran

来源：

MONATSHEFTE FUR CHEMIE | 2013年 / 144卷 / 12期

关键词：

Nano silica-supported tin(II) chloride; Heterogeneous catalysis; Biginelli reaction; One-pot synthesis; ONE-POT SYNTHESIS; SOLVENT-FREE SYNTHESIS; MAGNETICALLY RECOVERABLE CATALYST; BIGINELLI REACTION; REUSABLE CATALYST; IMPROVED PROTOCOL; SULFURIC-ACID; EFFICIENT; DIHYDROPYRIMIDINONES; 3,4-DIHYDROPYRIMIDIN-2(1H)-ONES;

D O I：

10.1007/s00706-013-1068-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Efficient, green, and straightforward synthesis of 3,4-dihydropyrimidine-2(1H)-one/thione derivatives under favorable conditions has been achieved by reaction of urea/thiourea, aldehydes, and ethyl acetoacetate, using the synthetic potential of nanosilica-supported tin(II) chloride. It is noteworthy that the procedure has many advantages, for example excellent product yields, short reaction time, easy isolation of products, and reusability of catalyst. .

引用

页码：1865 / 1870

页数：6

共 50 条

[21] Facile and Rapid Synthesis of 3,4-Dihydropyrimidin-2(1H)-one Derivatives Using [Et3NH][HSO4] as Environmentally Benign and Green Catalyst
Pouramiri, Behjat
Fayazi, Raziye
Tavakolinejad Kermani, Esmat
IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION, 2018, 37 (01): : 159 - 167
[22] Borax: An Ecofriendly and Efficient Catalyst for One-Pot Synthesis of 3,4-Dihydropyrimidine-2(1H)-ones under Solvent-Free Conditions
Nath, Jayashree
Chaudhuri, Mihir K.
SYNTHETIC COMMUNICATIONS, 2010, 40 (20) : 2976 - 2982
[23] Nano SbCl5•SiO2: An efficient and heterogeneous catalyst for synthesis of 3,4-dihydropyrimidin-2(1H)-one (thione) derivatives under solvent-free conditions
Bamoniri, A.
Mirjalili, B. F.
Karbasizadeh, H.
SCIENTIA IRANICA, 2015, 22 (06) : 2332 - 2340
[24] SYNTHESIS AND PHOTOPHYSICAL STUDIES ON 5-ETHOXYCARBONYL-4-CINNAMYL-6-METHYL-3,4-DIHYDROPYRIMIDINE-2(1H)-ONE IN VARIOUS SOLVENTS
Lad, Sheela N.
Mote, Umesh S.
Bhattar, Swaminath L.
Anbhule, Prashant V.
Patil, Shivajirao R.
Kolekar, Govind B.
BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA, 2009, 23 (02) : 231 - 238
[25] THE SYNTHESIS OF 3,4-DIHYDROPYRIMIDIN-2(1H)-ONE/ THIONE DERIVATIVES USING SILICA-SUPPORTED 3-(TRIETHOXYSILYL) PROPAN-1-AMMONIUM CHLORIDE AS REUSABLE HETEROGENEOUS CATALYST UNDER SOLVENTFREE CONDITIONS AND MICROWAVE
Ranjbar-Karimi, Reza
Khezri, Aliyeh Khajeh
Anary-Abbasinejad, Mohammad
HETEROCYCLIC LETTERS, 2014, 4 (02): : 301 - 310
[26] Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones, -thione, and -selones, Catalyzed by TiO2 Nanoparticles
Mohammadi, B.
Behbahani, F. K.
Marandi, G. B.
Mirza, B.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 58 (09) : 1319 - 1326
[27] Synthesis of some new bis-3,4-dihydropyrimidin-2(1H)-ones by using silica-supported tin chloride and titanium tetrachloride
Niknam, Khodabakhsh
Hasaninejad, Alireza
Arman, Madihe
CHINESE CHEMICAL LETTERS, 2010, 21 (04) : 399 - 402
[28] NaHSO4•H2O as a Heterogeneous Acidic Reagent for Mild and Convenient Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones and Their Sulfur Derivatives
Zeynizadeh, Behzad
Dilmaghani, Karim Akbari
Yari, Mahdi
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2009, 184 (09) : 2465 - 2471
[29] 12-molybdophosphoric acid: A recyclable catalyst for the synthesis of Biginelli-type 3,4-dihydropyrimidine-2(1H)-ones
Heravi, Majid M.
Bakhtiari, Khadijeh
Bamoharram, Fatemeh F.
CATALYSIS COMMUNICATIONS, 2006, 7 (06) : 373 - 376
[30] Study of catalytic activity of ammonium dihydrogen orthophosphate in the synthesis of 3,4-dihydropyrimidin-2-(1H)-one
Ramatchandiran, N.
Sumathi, S.
Buvaneswari, G.
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2009, 48 (06): : 865 - 867

← 1 2 3 4 5 →