Polyurethane-Modified Epoxy Monoacrylates Containing Two Different UV-Curable Groups: Preparation and Charaterization

被引:1
作者
Lin, Feng [1 ]
Liu, Hongbo [1 ]
Xu, Ling [1 ]
Zhang, Wuying [1 ]
机构
[1] Shenzhen Polytech, Sch Appl Chem & Biol Technol, Shenzhen 518055, Peoples R China
来源
ADVANCES IN CHEMISTRY RESEARCH II, PTS 1-3 | 2012年 / 554-556卷
关键词
preparation; UV curable; charaterization; photopolymerization; ACRYLATE;
D O I
10.4028/www.scientific.net/AMR.554-556.168
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Polyurethane-modified epoxy monoacrylates (PMEMA) containing two different UV-curable groups (double bond and epoxy groups) were synthesized. The changes of NCO groups during the synthesis process of PMEMA were measured by chemical titration method, and its Fourier Transform Infrared (FTIR) spectra were investigated. The results indicated that polyurethane chain segments can be grafted onto the epoxy monacrylates (EMA) by the reaction of NCO and OH groups. The FUR of PMEMA showed that it contains both double bond of acrylic ester (UV radical curable) and epoxy groups (UV cationic curable).
引用
收藏
页码:168 / 171
页数:4
相关论文
共 50 条
[21]   Design and preparation of UV-curable waterborne polyurethane based on novel fluorinated chain extender [J].
Shan, Changli ;
Ning, Chuang ;
Lou, Jingjie ;
Xu, Wei ;
Zhang, Yingqiang .
POLYMER BULLETIN, 2021, 78 (04) :2067-2083
[22]   Cationic UV-curable fluorine-containing polyacrylic epoxy prepolymer with good compatibility [J].
Zhao, Liyan ;
Wei, Mengying ;
Nie, Jun ;
He, Yong .
PROGRESS IN ORGANIC COATINGS, 2016, 100 :70-75
[23]   Preparation and characterization of UV-Curable MPS-modified silica nanocomposite coats [J].
Li, FS ;
Zhou, SX ;
Wu, LM .
JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 98 (05) :2274-2281
[24]   UV-Curable Silicone-Modified Polyurethane Acrylates for Food Freshness Monitoring [J].
He, Na ;
Zhu, Hongyu ;
Sun, Nana ;
Shi, Shaoqing ;
Xie, Libo ;
Miao, Jie ;
Lai, Guoqiao ;
Li, Meijiang ;
Yang, Xiongfa .
COATINGS, 2024, 14 (06)
[25]   Preparation and Properties of UV-Curable Waterborne Polyurethane Acrylate/MXene Nanocomposite Films [J].
Wang, Ying ;
Zhang, Shuai ;
Lin, Yanli ;
Wang, Qianyi ;
Zhang, Ying ;
Sun, Changmei ;
Qu, Rongjun .
NANOMATERIALS, 2023, 13 (23)
[26]   Preparation of epoxy-based silicone prepolymers with applications in UV-curable coatings [J].
Bian, Fuping ;
Lin, Shudong .
PIGMENT & RESIN TECHNOLOGY, 2024, 53 (05) :650-658
[27]   Synthesis and properties of UV-curable polyurethane acrylates containing fluorinated acrylic monomer/vinyltrimethoxysilane [J].
Jeong Min Park ;
Jae Hwan Jeon ;
Young Hee Lee ;
Dong Jin Lee ;
Hyun Park ;
Ho Hwan Chun ;
Han Do Kim .
Polymer Bulletin, 2015, 72 :1921-1936
[28]   Preparation and properties of CO2-based polyurethane acrylate UV-curable resins [J].
Zhao, Mingming ;
Bao, Junjie ;
Huang, Yiping .
Jingxi Huagong/Fine Chemicals, 2024, 41 (11) :2433-2439
[29]   Preparation and properties of UV-curable waterborne graphene oxide/polyurethane-acrylate composites [J].
Dai, Y. T. ;
Qiu, F. X. ;
Xu, J. C. ;
Yu, Z. P. ;
Yang, P. F. ;
Xu, B. B. ;
Jiang, Y. ;
Yang, D. Y. .
PLASTICS RUBBER AND COMPOSITES, 2014, 43 (02) :54-62
[30]   Preparation and properties of UV-curable diamine-based polyurethane acrylate hard coatings [J].
Fu, Junchao ;
Yu, Haojie ;
Wang, Li ;
Fahad, Shah .
APPLIED SURFACE SCIENCE, 2020, 533