2,2′:6′,2"-Terpyridine meets 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine: tuning the electro-optical properties of ruthenium(II) complexes

被引：108

作者：

Schulze, Benjamin ^{[1
,2
]}

Friebe, Christian ^{[1
,2
]}

Hager, Martin D. ^{[2
]}

Winter, Andreas ^{[2
]}

Hoogenboom, Richard ^{[2
]}

Goerls, Helmar ^{[3
]}

Schubert, Ulrich S. ^{[1
,2
]}

机构：

[1] Univ Jena, Lab Organ & Macromol Chem, D-07743 Jena, Germany

[2] Eindhoven Univ Technol, Lab Macromol Chem & Nanosci, NL-5600 MB Eindhoven, Netherlands

[3] Univ Jena, Inorgan & Analyt Chem Lab, D-07743 Jena, Germany

来源：

DALTON TRANSACTIONS | 2009年 / 05期

关键词：

CLICK CHEMISTRY; SPECTROSCOPIC PROPERTIES; EFFICIENT SYNTHESIS; POLYMERS; AZIDES; CYCLOADDITION; ROTAXANES; DONOR;

D O I：

10.1039/b813925c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a series of heteroleptic ruthenium(II)-complexes containing both, 2,2':6',2 ''-terpyridine and 2,6-bis(1H-1,2,3-triazol-4-yl)pyridine, is reported for the first time. The provided complexes feature photophysical and electrochemical properties in between those known for the respective homoleptic complexes. The flexibility with respect to lateral functional groups to be introduced into the complexes underlines the high potential for further functionalization steps.

引用

页码：787 / 794

页数：8

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