Carboxyl-Functionalized Task-Specific Ionic Liquids for Solubilizing Metal Oxides

被引：213

作者：

Nockemann, Peter ^{[1
]}

Thijs, Ben ^{[1
]}

Parac-Vogt, Tatjana N. ^{[1
]}

Van Hecke, Kristof ^{[1
]}

Van Meervelt, Luc ^{[1
]}

Tinant, Bernard ^{[2
]}

Hartenbach, Ingo ^{[3
]}

Schleid, Thomas ^{[3
]}

Ngan, Vu Thi ^{[1
]}

Nguyen, Minh Tho ^{[1
]}

Binnemans, Koen ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Chem, B-3001 Louvain, Belgium

[2] Catholic Univ Louvain, Unite CSTR, B-1348 Louvain, Belgium

[3] Univ Stuttgart, Inst Anorgan Chem, D-70569 Stuttgart, Germany

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 21期

关键词：

D O I：

10.1021/ic801213z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Imidazolium, pyridinium, pyrrolidinium, piperidinium, morpholinium, and quaternary ammonium bis(trifluoromethyl-sulfonyl)imide salts were functionalized with a carboxyl group. These ionic liquids are useful for the selective dissolution of metal oxides and hydroxides. Although these hydrophobic ionic liquids are immiscible with water at room temperature, several of them form a single phase with water at elevated temperatures. Phase separation occurs upon cooling. This thermomorphic behavior has been investigated by H-1 NMR, and it was found that it can be attributed to the temperature-dependent hydration and hydrogen-bond formation of the ionic liquid components. The crystal structures of four ionic liquids and five metal complexes have been determined.

引用

页码：9987 / 9999

页数：13

共 79 条

[11]

*BRUK AN XRAY SYST, 1997, SAINT MAN VERS 5 6 0, P84102

[12]

*BRUK AN XRAY SYST, 1997, SHELXTL PC MAN VERS, P84102

[13] Carboxyl-functional ionic liquids as scavengers: Case studies on benzyl chloride, amines, and methanesulfonyl chloride [J].

Cai, Yueqin ;

Zhang, Ying ;

Peng, Yanqing ;

Lu, Feng ;

Huang, Xinglong ;

Song, Gonghua .

JOURNAL OF COMBINATORIAL CHEMISTRY, 2006, 8 (05) :636-638

[14] METAL-BETAINE INTERACTIONS .17. A STUDY OF INTRADIMER CU...CU DISTANCE VARIATION IN COPPER(II) BETAINE COMPLEXES CONTAINING [CU2(CARBOXYLATO-O,O')4L2]N+ SPECIES [J].

CHEN, XM ;

MAK, TCW .

STRUCTURAL CHEMISTRY, 1993, 4 (04) :247-259

[15] Liquid phase behavior of ionic liquids with alcohols: Experimental studies and modeling [J].

Crosthwaite, JM ;

Muldoon, MJ ;

Aki, SNVK ;

Maginn, EJ ;

Brennecke, JF .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (18) :9354-9361

[16] Task-specific ionic liquids [J].

Davis, JH .

CHEMISTRY LETTERS, 2004, 33 (09) :1072-1077

[17] Synthesis, IR and NMR studies of zwitterionic ω-(1-pyrrolidine)alkanocarboxylic acids and their N-methyl derivatives [J].

Dega-Szafran, Z ;

Przybylak, R .

JOURNAL OF MOLECULAR STRUCTURE, 1997, 437 :107-121

[18] Structure, conformation and hydrogen bonding of 4-(N-methylpiperidinium)-butyric acid bromide [J].

Dega-Szafran, Z. ;

Dulewicz, E. ;

Szafran, M. ;

Thaimattam, R. ;

Jaskolski, M. .

JOURNAL OF MOLECULAR STRUCTURE, 2007, 828 (1-3) :19-24

[19] FTIR, 1H and 13C NMR spectra of 1:1 complexes of 1-piperidineacetic acid and N-methylpiperidine betaine with mineral acids [J].

Dega-Szafran, Z ;

Dulewicz, E ;

Petryna, M .

JOURNAL OF MOLECULAR STRUCTURE, 2003, 651 :635-644

[20] Crystal and molecular structure of N-methylpiperidine betaine hydrochloride [J].

Dega-Szafran, Z ;

Szafran, M ;

Dulewicz, E ;

Addlagatta, A ;

Jaskólski, M .

JOURNAL OF MOLECULAR STRUCTURE, 2003, 654 (1-3) :71-80

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